ArticleScience (New York, N.Y.)2024
Synthetic dioxygenase reactivity by pairing electrochemical oxygen reduction and water oxidation.
Article in Science (New York, N.Y.), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
17 citing papers in PubMed, 75 citations in OpenAlex.
- Electrocatalytic polyvinylidene fluoride defluorination with water mediation at room temperature.Science advances · 2026Article
- Spatially harnessing oxygenase enables paired and ultraselective electrooxidative waste depolymerization.Nature communications · 2026Article
- Heterogeneous Indirect Redox Electrocatalysis in Electrolyte.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- A paired electrolysis for hydroxymethanesulfonate synthesis using sulfide waste as the sulfur source.Nature communications · 2026Article
- Electrochemical Oxygen-Atom Transfer to Alkenes and Pyridines with a Mn-Porphyrin Catalyst Using Water as the Source of Oxygen.ACS catalysis · 2026Article
- Electrochemical hydroxylation of alkenes with HNational science review · 2026Article
- Bright Sparks of Single-Atom and Nano-Islands in Catalysis: Breaking Activity-Stability Trade-Off.Nano-micro letters · 2026Review
- Formal anti-Markovnikov hydration of alkenes via paired electrolysis intercepting water-splitting.Nature communications · 2026Article
- Ultrafast energy-neutral molecular oxygen activation via atomically-adjacent bimetallic catalytic sites.Nature communications · 2025Article
- Oxyanions stabilized low-coordinated nickel species for efficient and durable nucleophilic electrooxidation.Nature communications · 2025Article
- High Oxidation State V-O-Co Structure Promotes the Role of V-Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Paired Chemical Upgrading in Photoelectrochemical Cells.JACS Au · 2025Review
- Cathodic oxygen reduction-enabled rhodium-catalyzed (5 + 1) C-H/O-H annulation inspired by fuel cells.Nature communications · 2025Article
- Donor-acceptor engineering of a triplet-exciton-optimized MOF photocatalyst for efficient singlet oxygen-mediated oxidation.National science review · 2025Article
- Molybdenum tungsten hydrogen oxide doped with phosphorus for enhanced oxygen/hydrogen evolution reactions.RSC advances · 2024Article
- Dioxygenase Chemistry in Nucleophilic Aldehyde Deformylations Utilizing Dicopper OJournal of the American Chemical Society · 2024Article
- Manganese-Mediated Electrochemical Oxidation of Thioethers to Sulfoxides Using Water as the Source of Oxygen Atoms.Journal of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
The reactivity of molecular oxygen is crucial to clean energy technologies and green chemical synthesis, but kinetic barriers complicate both applications. In synthesis, dioxygen should be able to undergo oxygen atom transfer to two organic molecules with perfect atom economy, but such reactivity is rare. Monooxygenase enzymes commonly reductively activate dioxygen by sacrificing one of the oxygen atoms to generate a more reactive oxidant. Here, we used a manganese-tetraphenylporphyrin catalyst to pair electrochemical oxygen reduction and water oxidation, generating a reactive manganese-oxo at both electrodes. This process supports dioxygen atom transfer to two thioether substrate molecules, generating two equivalents of sulfoxide with a single equivalent of dioxygen. This net dioxygenase reactivity consumes no electrons but uses electrochemical energy to overcome kinetic barriers.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.