ArticleNanomaterials (Basel, Switzerland)2024
Stability of Zr-Based UiO-66 Metal-Organic Frameworks in Basic Solutions.
Article in Nanomaterials (Basel, Switzerland), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Sustainable synthesis of a Zr-based UiO-66 MOF from PET waste for UV-assisted degradation of organic contaminants.RSC advances · 2026Article
- Multifunctional UiO-66 MOFs in Photocatalytic and Electrocatalytic Nitrogen Reduction: A New Horizon in Green Ammonia Synthesis.ACS organic & inorganic Au · 2026Review
- Sustainable synthesis of Ag/UiO-66 composites using recycled silver for efficient adsorption of methylene blue and crystal violet.Scientific reports · 2026Article
- Catalyst Hide-and-Seek Beneath Porous Support Surfaces: Pinpointing Active Site Distribution Through Resonance Energy Transfer.Angewandte Chemie (International ed. in English) · 2026Article
- Next-generation electrochemical aptasensors for thrombin detection: the rise of aptamer-MOF architectures.Analytical and bioanalytical chemistry · 2026Review
- Metal-Organic Frameworks as Room Temperature Chemiresistive Ammonia Gas Sensing Material: A Review.Sensors (Basel, Switzerland) · 2026Review
- UiO-66 metal-organic frameworks in biomedicine: From structural tunability to bioimaging, photodiagnostics, and photodynamic cancer therapy.FEBS open bio · 2026Review
- Boosting Photocatalytic COMolecules (Basel, Switzerland) · 2026Article
- Review
- Mapping the Hierarchical Environmental Transformations of Nanoscale UiO-66 Metal-organic Framework.Environmental science & technology · 2026Article
- Zr-gallic acid based metal organic compound as adsorbent for extraction of uranium(vi) from nitrate solution: adsorption behaviors and mechanisms.RSC advances · 2026Article
- Review
- Encapsulation of a Highly Acid-Stable Dicyano-Bodipy in Zr-Based Metal-Organic Frameworks with Increased Fluorescence Lifetime and Quantum Yield Within the Solid Solution Concept.Molecules (Basel, Switzerland) · 2025Article
- Application of UiO-66 MOF for rifampicin removal and post-adsorption antimicrobial activity against MRSA.Scientific reports · 2025Article
- Metal-Organic Framework (MOF)-Based Micro/Nanoscale Materials.Nanomaterials (Basel, Switzerland) · 2025Article
- Metal-organic frameworks (MOFs) for arsenic remediation: a brief overview of recent progress.RSC advances · 2025Review
- The performance of hybrid materials for the biodegradation of dichloromethane using Pseudomonas aeruginosa, coconut shell, rice husk, and metal organic framework.Biodegradation · 2025Article
- Chitinase-functionalized UiO-66 framework nanoparticles active against multidrug-resistant Candida Auris.BMC microbiology · 2024Article
- Deep Oxidative Desulfurization of Planar Compounds Over Functionalized Metal-Organic Framework UiO-66(Zr): An Optimization Study.ACS omega · 2024Article
- Positional functionalizations of metal-organic frameworks through invasive ligand exchange and additory MOF-on-MOF strategies: A review.Smart molecules : open access · 2024Review
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
Although Zr-based metal-organic frameworks (MOFs) exhibit robust chemical and physical stability in the presence of moisture and acidic conditions, their susceptibility to nucleophilic attacks from bases poses a critical challenge to their overall stability. Herein, we systematically investigate the stability of Zr-based UiO-66 (UiO = University of Oslo) MOFs in basic solutions. The impact of 11 standard bases, including inorganic salts and organic bases, on the stability of these MOFs is examined. The destruction of the framework is confirmed through powder X-ray diffraction (PXRD) patterns, and the monitored dissolution of ligands from the framework is assessed using nuclear magnetic resonance (NMR) spectroscopy. Our key findings reveal a direct correlation between the strength and concentration of the base and the destruction of the MOFs. The summarized data provide valuable insights that can guide the practical application of Zr-based UiO-66 MOFs under basic conditions, offering essential information for their optimal utilization in various settings.
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Registered trials
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