Evidence map›Paper›PMID 38186925›Full record

ArticleACS catalysis2020

Enantioselective Alkynylation of Unstabilized Cyclic Iminium Ions.

Weiye Guan, Samantha O Santana, Jennie Liao, Kelci Henninger, Mary P Watson

Open access · greenAbstract read
In one paragraph

Article in ACS catalysis, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
2.1field-weighted citation impact, top 13% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 31 citations in OpenAlex.

  1. Article
  2. Article
  3. Oxidative Cross Dehydrogenative Coupling ofJournal of the American Chemical Society · 2023
    Article
  4. Article
  5. Copper catalyzed late-stage C(spNature communications · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 1 institution in 1 country.

Weiye GuanDepartment of Chemistry & Biochemistry, University of Delaware, Newark, Delaware 19716, United States.
Samantha O SantanaDepartment of Chemistry & Biochemistry, University of Delaware, Newark, Delaware 19716, United States.
Jennie LiaoDepartment of Chemistry & Biochemistry, University of Delaware, Newark, Delaware 19716, United States.
Kelci HenningerDepartment of Chemistry & Biochemistry, University of Delaware, Newark, Delaware 19716, United States.
Mary P WatsonDepartment of Chemistry & Biochemistry, University of Delaware, Newark, Delaware 19716, United States.
University of Delaware · US

Funding

This renovation project will create over 1455 sq. ft. of state- of-the-art reseaP20GM104316 · NIGMS · UNIVERSITY OF DELAWARE · PI SCHMITZ, KARL ROBERT · 2014 to 2024
$26.8M
Molecular Design of Advanced BiomaterialsP20GM103541 · NIGMS · UNIVERSITY OF DELAWARE · PI POLENOVA, TATYANA · 2012 to 2012
$2.1M
Q-Exactive Orbitrap LC-MC/MS SystemS10OD016267 · OD · UNIVERSITY OF DELAWARE · PI JOHNSTON, MURRAY V · 2013 to 2013
$573k
NIGMS NIH HHS P20 GM103541NIGMS NIH HHS P20 GM104316NIH HHS S10 OD016267
6 · The paper itself

Abstract

An enantioselective copper-catalyzed alkynylation of unstabilized cyclic iminium ions has been developed. Whereas such alkynylations typically utilize pyridinium, quinolinium and isoquinolinium intermediates, this method enables use of cyclic iminium ions unstabilized by resonance. With the use of a Lewis acid and copper catalyst, these iminium ions are generated

Indexed as

alkynylationcopper catalysisenantioselective catalysisHammett correlationnitrogen heterocycles

Identifiers

PMID38186925
PMCPMC10769448
OpenAlexW3106348827

What OpenQuestion holds

Textmetadata
LicenceTDM
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.