Evidence map›Paper›PMID 38179536›Full record

ArticleChemical science2024

Lewis acid catalysed polymerisation of cyclopentenone.

Deepamali Dissanayake, Alysia Draper, Zhizhou Liu, Neelofur Jaunnoo, Joris J Haven, Craig Forsyth, Alasdair I McKay, Tanja Junkers, Dragoslav Vidović

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Deepamali DissanayakeSchool of Chemistry, Monash University Clayton 3800 Australia drasko.vidovic@monash.edu tanja.junkers@monash.edu.
Alysia DraperSchool of Chemistry, Monash University Clayton 3800 Australia drasko.vidovic@monash.edu tanja.junkers@monash.edu.
Zhizhou LiuSchool of Chemistry, Monash University Clayton 3800 Australia drasko.vidovic@monash.edu tanja.junkers@monash.edu.
Neelofur JaunnooSchool of Chemistry, Monash University Clayton 3800 Australia drasko.vidovic@monash.edu tanja.junkers@monash.edu.
Joris J HavenSchool of Chemistry, Monash University Clayton 3800 Australia drasko.vidovic@monash.edu tanja.junkers@monash.edu.
Craig ForsythSchool of Chemistry, Monash University Clayton 3800 Australia drasko.vidovic@monash.edu tanja.junkers@monash.edu.ORCID https://orcid.org/0000-0002-3433-6130
Alasdair I McKaySchool of Chemistry, Monash University Clayton 3800 Australia drasko.vidovic@monash.edu tanja.junkers@monash.edu.ORCID https://orcid.org/0000-0002-6859-172X
Tanja JunkersSchool of Chemistry, Monash University Clayton 3800 Australia drasko.vidovic@monash.edu tanja.junkers@monash.edu.ORCID https://orcid.org/0000-0002-6825-5777
Dragoslav VidovićSchool of Chemistry, Monash University Clayton 3800 Australia drasko.vidovic@monash.edu tanja.junkers@monash.edu.ORCID https://orcid.org/0000-0003-4269-3995

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A modest structural change of a β-diketiminate-supported aluminium complex leads to dramatic differences in the reactivity towards cyclopentenone. While the bulkier complex efficiently executes Diels Alder transformations the smaller analogue performs unique polymerisation of this substrate. This observation appears to be unprecedented in the chemistry of Lewis acids and cyclic dienophiles as it represents a unique way to polymerise a functionalised olefin.

Identifiers

PMID38179536
PMCPMC10762972

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.