ArticleChemical science2024
Boosting quantum yields and circularly polarized luminescence of penta- and hexahelicenes by doping with two BN-groups.
Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed, 33 citations in OpenAlex.
- Enantioselective synthesis of configurationally stable [5]helicenes containing 1,2-azaborine units.Chemical science · 2026Article
- Quantum Chemistry Calculations of Circularly Polarized Luminescence (CPL): From Spectral Modeling to Molecular Design.Chemical reviews · 2025Review
- Acid/Base-Responsive Circularly Polarized Luminescence Emitters with Configurationally Stable Nitrogen Stereogenic Centers.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- COMPAS-4: A Data Set of (BN)Journal of chemical information and modeling · 2025Article
- Axial chirality-induced rigidification in aminoboranes enhances persistent room-temperature phosphorescence and circularly polarized luminescence.Communications chemistry · 2025Article
- Boron-containing helicenes as new generation of chiral materials: opportunities and challenges of leaving the flatland.Chemical science · 2024Review
- A highly fluorescent bora[6]helicene exhibiting circularly polarized light emission.Chemical science · 2024Article
Corrections and comments
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Authors and funding
11 authors at 3 institutions in 3 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The incorporation of boron-nitrogen (BN) units into polycyclic aromatic hydrocarbons (PAHs) as an isoelectronic replacement of two carbon atoms can significantly improve their optical properties, while the geometries are mostly retained. We report the first non-π-extended penta- and hexahelicenes comprising two aromatic 1,2-azaborinine rings. Comparing them with their all-carbon analogs regarding structural, spectral and (chir)optical properties allowed us to quantify the impact of the heteroatoms. In particular, BN-hexahelicene BN[6] exhibited a crystal structure congruent with its analog CC[6], but displayed a fivefold higher fluorescence quantum yield (
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Registered trials
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