Aldiminium and 1,2,3-triazolium dithiocarboxylate zwitterions derived from cyclic (alkyl)(amino) and mesoionic carbenes.

Nedra Touj, François Mazars, Guillermo Zaragoza, Lionel Delaude

Open access · diamondAbstract read

In one paragraph

Article in Beilstein journal of organic chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it

0cells of the map it votes in

0citing papers in PubMed

1.5field-weighted citation impact, top 19% of its field

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 10 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 2 institutions in 2 countries.

Nedra ToujLaboratory of Catalysis, MolSys Research Unit, Université de Liège, Institut de chimie organique (B6a), Allée du six août 13, 4000 Liège, Belgium.ORCID https://orcid.org/0000-0001-6071-4361

François MazarsLaboratory of Catalysis, MolSys Research Unit, Université de Liège, Institut de chimie organique (B6a), Allée du six août 13, 4000 Liège, Belgium.

Guillermo ZaragozaUnidad de Difracción de Rayos X, RIAIDT, Universidade de Santiago de Compostella, Edificio CACTUS, Campus Vida, 15782 Santiago de Compostela, Spain.ORCID https://orcid.org/0000-0002-2550-6628

Lionel DelaudeLaboratory of Catalysis, MolSys Research Unit, Université de Liège, Institut de chimie organique (B6a), Allée du six août 13, 4000 Liège, Belgium.ORCID https://orcid.org/0000-0002-1134-2992

University of Liège · BEUniversidade de Santiago de Compostela · ES

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The synthesis of zwitterionic dithiocarboxylate adducts was achieved by deprotonating various aldiminium or 1,2,3-triazolium salts with a strong base, followed by the nucleophilic addition of the in situ-generated cyclic (alkyl)(amino) or mesoionic carbenes (CAACs or MICs) onto carbon disulfide. Nine novel compounds were isolated and fully characterized by

Indexed as

betainescarbenesligand effectsnitrogen heterocycleszwitterions

Identifiers

PMID38170157

DOI10.3762/bjoc.19.145

PMCPMC10760461

OpenAlexW4390038491

What OpenQuestion holds

Textmetadata

LicenceCC BY

Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.