ArticleJournal of the American Chemical Society2024
Photoinduced Dynamic Ligation in Metal-Organic Frameworks.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed, 44 citations in OpenAlex.
- Photocatalytic Ammonia Synthesis using Fe-Based MOFs: The Role of Ligand Functionalization.Journal of the American Chemical Society · 2026Article
- Fe metal-organic framework-derived heterojunction for metabolic diagnosis of thymic epithelial tumor.Proceedings of the National Academy of Sciences of the United States of America · 2026Article
- Photoaccumulation of Long-Lived Reactive Electrons in a Microporous Ti(IV) Oxocluster-Based Metal-Organic Framework for Light and Dark Photocatalysis.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Spin Frustration Determines the Stability and Reactivity of Metal-Organic Frameworks with Triangular Iron(III)-Oxo Clusters.Angewandte Chemie (International ed. in English) · 2025Article
- Tuning the Lifetimes of Photoinduced Deligation in a Metal-Organic Framework via Linker Functionalization.Journal of the American Chemical Society · 2025Article
- Space-confined charge transfer turns on multicolor emission in metal-organic frameworks via pressure treatment.Nature communications · 2025Article
- Excited State Transient Phenomena in Two Different Phases of the Photoactive MOF MIP-177(Ti).Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Sequential addition of cations increases photoluminescence quantum yield of metal nanoclusters near unity.Nature communications · 2025Article
- Microwave-Assisted Synthesis of CdS-MOF MIL-101 (Fe) Composite: Characterization and Photocatalytic Performance.Inorganic chemistry · 2024Article
Corrections and comments
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Authors and funding
6 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Metal organic frameworks (MOFs), a class of porous crystalline materials consisting of metal-based nodes and organic linkers, have emerged as a promising platform for photocatalysis due to their ultrahigh functional surface area, customizable topologies, and tunable energetics. While interesting photochemistry has been reported, the related photoinduced structural dynamics of MOFs remains unclear. The consensus is that the coordination bonds between MOF nodes and linkers are considered static during photoexcitation, while the open-metal sites on the nodes are taken as the key active sites for catalysis. In this work, through a complementary time-resolved visible and infrared (IR) spectroscopic investigation, along with computational studies, we report for the first time light-induced structural bond dissociation (COO-M) and reformation in an iron-oxo framework, MIL-101(Fe). The probed excited state displayed ligand-to-metal charge transfer (LMCT) characteristics and exhibited a
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.