ArticleNature communications2023
Stoichiometry validation of supramolecular complexes with a hydrocarbon cage host by van 't Hoff analyses.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
4 citing papers in PubMed, 10 citations in OpenAlex.
- Molecular Insights into the Separation of Iron by 18-Crown‑6 Ethers from Hydrochloric Acid.ACS omega · 2026Article
- Coordination-Driven Scrambling in Tricopper(I) Clusters: Thermodynamic Insights into Dynamic Assembly.Inorganic chemistry · 2026Article
- High-Order Host-Guest Complexation of Structurally Well-Defined Cycloparaphenylene Double-Deckers with Fullerenes.Precision chemistry · 2025Article
- Expanded segments of three-dimensional carbonaceous nets with chirality: synthesis and structures.Chemical science · 2025Article
Corrections and comments
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Authors and funding
5 authors at 1 institution in 1 country.
Funding
Abstract
Defining chemical processes with equations is the first important step in characterizing equilibria for the assembly of supramolecular complexes, and the stoichiometry of the assembled components must be defined to generate the equation. Recently, this subject has attracted renewed interest, and statistical and/or information-theoretic measures were introduced to examine the validities of the equilibrium models used during curve fitting analyses of titration. The present study shows that these measures may not always be appropriate for credibility examinations and that further reformation of the protocols used to determine the overall stoichiometry is necessary. Hydrocarbon cage hosts and their chloroform complexes formed via weak CH-π hydrogen bonds were studied, which allowed us to introduce van 't Hoff analyses for effective validation of the stoichiometries of supramolecular complexes. This study shows that the stoichiometries of supramolecular complexes should be carefully examined by adopting multiple measures with different origins.
Identifiers
What OpenQuestion holds
Registered trials
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