Evidence map›Paper›PMID 38109537›Full record

ArticleProceedings of the National Academy of Sciences of the United States of America2023

Observation of the most H

Umbertoluca Ranieri, Simone Di Cataldo, Maria Rescigno, Lorenzo Monacelli, Richard Gaal, Mario Santoro, Leon Andriambariarijaona, Paraskevas Parisiades, Cristiano De Michele, Livia Eleonora Bove

Open access · hybridAbstract read
In one paragraph

Article in Proceedings of the National Academy of Sciences of the United States of America, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
2.0field-weighted citation impact, top 15% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 14 citations in OpenAlex.

  1. Review
  2. Article
  3. Dual quantum locking: Dynamic coupling of HProceedings of the National Academy of Sciences of the United States of America · 2026
    Article
  4. Article
  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors at 5 institutions in 5 countries.

Umbertoluca Ranieri *Dipartimento di Fisica, Sapienza Università di Roma, 00185 Roma, Italy.ORCID 0000-0003-2026-6132
Simone Di Cataldo *Dipartimento di Fisica, Sapienza Università di Roma, 00185 Roma, Italy.ORCID 0000-0002-8902-0125
Maria RescignoDipartimento di Fisica, Sapienza Università di Roma, 00185 Roma, Italy.
Lorenzo MonacelliTheory and Simulation of Materials, and National Centre for Computational Design and Discovery of Novel Materials, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland.
Richard GaalLaboratory of Quantum Magnetism, Institute of Physics, École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland.ORCID 0000-0001-5181-423X
Mario SantoroConsiglio Nazionale delle Ricerche, Istituto Nazionale di Ottica, CNR-INO, Sesto Fiorentino, 50019, Italy.ORCID 0000-0001-5693-4636
Leon AndriambariarijaonaSorbonne Université, UMR CNRS 7590, Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie, 75252 Paris, France.ORCID 0009-0007-8302-4436
Paraskevas ParisiadesSorbonne Université, UMR CNRS 7590, Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie, 75252 Paris, France.ORCID 0000-0001-6962-264X
Cristiano De MicheleDipartimento di Fisica, Sapienza Università di Roma, 00185 Roma, Italy.ORCID 0000-0002-8367-0610
Livia Eleonora BoveDipartimento di Fisica, Sapienza Università di Roma, 00185 Roma, Italy.ORCID 0000-0003-1386-8207
Centre National de la Recherche Scientifique · FRÉcole Polytechnique Fédérale de Lausanne · CHSapienza University of Rome · ITNational Institute of Optics · ITTU Wien · AT

Funding

SNF 212889
6 · The paper itself

Abstract

Hydrogen hydrates are among the basic constituents of our solar system's outer planets, some of their moons, as well Neptune-like exo-planets. The details of their high-pressure phases and their thermodynamic conditions of formation and stability are fundamental information for establishing the presence of hydrogen hydrates in the interior of those celestial bodies, for example, against the presence of the pure components (water ice and molecular hydrogen). Here, we report a synthesis path and experimental observation, by X-ray diffraction and Raman spectroscopy measurements, of the most H[Formula: see text]-dense phase of hydrogen hydrate so far reported, namely the compound 3 (or C[Formula: see text]). The detailed characterisation of this hydrogen-filled ice, based on the crystal structure of cubic ice I (ice I[Formula: see text]), is performed by comparing the experimental observations with first-principles calculations based on density functional theory and the stochastic self-consistent harmonic approximation. We observe that the extreme (up to 90 GPa and likely beyond) pressure stability of this hydrate phase is due to the close-packed geometry of the hydrogen molecules caged in the ice I[Formula: see text] skeleton.

Indexed as

ab initio simulationsclathrate hydrateshigh pressurephase transitionsRaman

Identifiers

PMID38109537
PMCPMC10756306
OpenAlexW4389887706

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.