ArticleChemistry of materials : a publication of the American Chemical Society2023
Insight into the Isoreticularity of Li-MOFs for the Design of Low-Density Solid and Quasi-Solid Electrolytes.
Article in Chemistry of materials : a publication of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors at 1 institution in 1 country.
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Abstract
Isoreticularity in metal organic frameworks (MOFs) allows the design of the framework structure and tailoring the pore aperture at the molecular level. The optimal pore volume, long-range order of framework expansion, and crystallite size (grain size) could enable improving Li-ion conduction, thereby providing a unique opportunity to design high-performance solid and quasi-solid electrolytes. However, definitive understanding of the pore aperture, framework expansion, and crystallite size on the Li-ion conduction and its mechanism in MOFs remains at the exploratory stage. Among the different MOF subfamilies, Li-MOFs created by the isoreticular framework expansion using dicarboxylates of benzene, naphthalene, and biphenyl building blocks emerge as low-density porous solids with exceptional thermal stability to study the solid-state Li
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