Evidence map›Paper›PMID 38107025›Full record

ArticleACS catalysis2020

Facilitating Ir-Catalyzed C-H Alkynylation with Electrochemistry: Anodic Oxidation-Induced Reductive Elimination.

Xiaohan Ye, Chenhuan Wang, Shuyao Zhang, Jingwen Wei, Chuan Shan, Lukasz Wojtas, Yan Xie, Xiaodong Shi

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ACS catalysis, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Xiaohan YeDepartment of Chemistry, University of South Florida, Tampa, FL 33620, USA.
Chenhuan WangDepartment of Chemistry, University of South Florida, Tampa, FL 33620, USA.
Shuyao ZhangDepartment of Chemistry, University of South Florida, Tampa, FL 33620, USA.
Jingwen WeiDepartment of Chemistry, University of South Florida, Tampa, FL 33620, USA.
Chuan ShanDepartment of Chemistry, University of South Florida, Tampa, FL 33620, USA.
Lukasz WojtasDepartment of Chemistry, University of South Florida, Tampa, FL 33620, USA.
Yan XieCollege of Chemistry and Materials Engineering, Quzhou University, Quzhou 324000, P.R.China.
Xiaodong ShiDepartment of Chemistry, University of South Florida, Tampa, FL 33620, USA.

Funding

Achieving challenging coupling with gold redox catalysisR01GM120240 · NIGMS · UNIVERSITY OF SOUTH FLORIDA · PI SHI, XIAODONG · 2016 to 2020
$1.6M
NIGMS NIH HHS R01 GM120240
6 · The paper itself

Abstract

An electrochemical approach in promoting directed C-H alkynylation with terminal alkyne via iridium catalysis is reported. This work employed anodic oxidation of Ir(III) intermediate (characterized by X-ray crystallography) to promote reductive elimination, giving the desired coupling products in good yields (up to 95%) without the addition of any other external oxidants. This transformation is suitable for various directing groups with H

Indexed as

alkynylationanodic oxidationC-H activationelectrochemistryiridium

Identifiers

PMID38107025
PMCPMC10723742

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.