Evidence map›Paper›PMID 38105796›Full record

ArticleChemCatChem2023

Synthesis of Ketonylated Carbocycles via Excited-State Copper-Catalyzed Radical Carbo-Aroylation of Unactivated Alkenes.

Satavisha Sarkar, Arghya Banerjee, Ming-Yu Ngai

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ChemCatChem, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Satavisha SarkarDepartment of Chemistry and Institute of Chemical Biology and Drug Discovery, State University of New York, Stony Brook, New York 11794-3400, USA.
Arghya BanerjeeDepartment of Chemistry and Institute of Chemical Biology and Drug Discovery, State University of New York, Stony Brook, New York 11794-3400, USA.
Ming-Yu NgaiDepartment of Chemistry and Institute of Chemical Biology and Drug Discovery, State University of New York, Stony Brook, New York 11794-3400, USA.

Funding

Novel Strategies and Reagents for Introduction of Fluorinated GroupsR35GM119652 · NIGMS · STATE UNIVERSITY NEW YORK STONY BROOK · PI Ming-Yu Ngai · 2016 to 2026
$4.8M
NIGMS NIH HHS R35 GM119652
6 · The paper itself

Abstract

Carbocycles are core skeletons in natural and synthetic organic compounds possessing a wide diversity of important biological activities. Herein, we report the development of an excited-state copper-catalyzed radical carbo-aroylation of unactivated alkenes to synthesize ketonylated tetralins, di- and tetrahydrophenanthrenes, and cyclopentane derivatives. The reaction is operationally simple and features mild reaction conditions that tolerate a broad range of functional groups. Preliminary mechanistic studies suggest a reaction pathway beginning with photoexcitation of [CuI-BINAP]

Indexed as

Aroyl ChloridesCopper PhotoredoxTetralin carbocyclesUnactivated alkenes

Identifiers

PMID38105796
PMCPMC10723085

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.