Evidence map›Paper›PMID 38098252›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2024

Advanced Soft Porous Organic Crystal with Multiple Gas-Induced Single-Crystal-to-Single-Crystal Transformations for Highly Selective Separation of Propylene and Propane.

Lin Li, Shuhong Zhao, Huiming Huang, Muyao Dong, Jie Liang, Hui Li, Jian Hao, Engui Zhao, Xinggui Gu

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
1.9field-weighted citation impact, top 15% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 19 citations in OpenAlex.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 3 institutions in 1 country.

Lin LiBeijing Advanced Innovation Center for Soft Matter Science and Engineering, State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Analysis and Test Center, Beijing University of Chemical Technology, Beijing University of Chemical Technology, Beijing, 100029, P. R. China.
Shuhong ZhaoBeijing Advanced Innovation Center for Soft Matter Science and Engineering, State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Analysis and Test Center, Beijing University of Chemical Technology, Beijing University of Chemical Technology, Beijing, 100029, P. R. China.
Huiming HuangBeijing Advanced Innovation Center for Soft Matter Science and Engineering, State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Analysis and Test Center, Beijing University of Chemical Technology, Beijing University of Chemical Technology, Beijing, 100029, P. R. China.
Muyao DongBeijing Advanced Innovation Center for Soft Matter Science and Engineering, State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Analysis and Test Center, Beijing University of Chemical Technology, Beijing University of Chemical Technology, Beijing, 100029, P. R. China.
Jie LiangBeijing Advanced Innovation Center for Soft Matter Science and Engineering, State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Analysis and Test Center, Beijing University of Chemical Technology, Beijing University of Chemical Technology, Beijing, 100029, P. R. China.
Hui LiBeijing Advanced Innovation Center for Soft Matter Science and Engineering, State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Analysis and Test Center, Beijing University of Chemical Technology, Beijing University of Chemical Technology, Beijing, 100029, P. R. China.
Jian HaoBeijing Advanced Innovation Center for Soft Matter Science and Engineering, State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Analysis and Test Center, Beijing University of Chemical Technology, Beijing University of Chemical Technology, Beijing, 100029, P. R. China.
Engui ZhaoSchool of Science, Harbin Institute of Technology, Shenzhen, HIT Campus of University Town, Shenzhen, 518055, P. R. China.
Xinggui GuBeijing Advanced Innovation Center for Soft Matter Science and Engineering, State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Analysis and Test Center, Beijing University of Chemical Technology, Beijing University of Chemical Technology, Beijing, 100029, P. R. China.ORCID https://orcid.org/0000-0002-1678-2823
Beijing University of Chemical Technology · CNBeijing National Laboratory for Molecular Sciences · CNHarbin Institute of Technology · CN

Funding

Beijing National Laboratory for Molecular Sciences BNLMS202103China Postdoctoral Science Foundation 2022TQ0162National Natural Science Foundation of China 22005050National Natural Science Foundation of China 52173145
6 · The paper itself

Abstract

Soft porous organic crystals with stimuli-responsive single-crystal-to-single-crystal (SCSC) transformations are important tools for unraveling their structural transformations at the molecular level, which is of crucial importance for the rapid development of stimuli-responsive systems. Carefully balancing the crystallinity and flexibility of materials is the prerequisite to construct advanced organic crystals with SCSC, which remains challenging. Herein, a squaraine-based soft porous organic crystal (SPOC-SQ) with multiple gas-induced SCSC transformations and temperature-regulated gate-opening adsorption of various C1-C3 hydrocarbons is reported. SPOC-SQ is featured with both crystallinity and flexibility, which enable pertaining the single crystallinity of the purely organic framework during accommodating gas molecules and directly unveiling gas-framework interplays by SCXRD technique. Thanks to the excellent softness of SPOC-SQ crystals, multiple metastable single crystals are obtained after gas removals, which demonstrates a molecular-scale shape-memory effect. Benefiting from the single crystallinity, the molecule-level structural evolutions of the SPOC-SQ crystal framework during gas departure are uncovered. With the unique temperature-dependent gate-opening structural transformations, SPOC-SQ exhibits distinctly different absorption behaviors towards C

Indexed as

gas separationgate openingmolecular-scale shape-memory effectsingle-crystal-to-single-crystalsoft porous organic crystals

Identifiers

PMID38098252
PMCPMC10916656
OpenAlexW4389790413

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.