Evidence map›Paper›PMID 38087461›Full record

ArticleThe Journal of organic chemistry2024

Supramolecular Large Nanosheets Assembled at Air/Water Interfaces and in Solution from Amphiphilic Heptagon-Containing Nanographenes.

Arthur H G David, Mari C Mañas-Torres, Marcos D Codesal, Irene López-Sicilia, María T Martín-Romero, Luis Camacho, Juan M Cuerva, Victor Blanco, Juan J Giner-Casares, Luis Álvarez de Cienfuegos and 1 more

Open access · hybridAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in The Journal of organic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
0.1field-weighted citation impact, top 54% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 1 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors at 2 institutions in 1 country.

Arthur H G DavidDepartamento de Química Orgánica, Facultad de Ciencias, Unidad de Excelencia Química Aplicada a Biomedicina y Medioambiente, Universidad de Granada, Avda. Fuente Nueva, s/n, 18071 Granada, Spain.ORCID 0000-0002-9275-2343
Mari C Mañas-TorresDepartamento de Química Orgánica, Facultad de Ciencias, Unidad de Excelencia Química Aplicada a Biomedicina y Medioambiente, Universidad de Granada, Avda. Fuente Nueva, s/n, 18071 Granada, Spain.
Marcos D CodesalDepartamento de Química Orgánica, Facultad de Ciencias, Unidad de Excelencia Química Aplicada a Biomedicina y Medioambiente, Universidad de Granada, Avda. Fuente Nueva, s/n, 18071 Granada, Spain.
Irene López-SiciliaDepartamento de Química Física y T. Aplicada, Instituto Químico para la Energía y Medioambiente IQUEMA, Facultad de Ciencias, Universidad de Córdoba, Campus de Rabanales, Ed. Marie Curie, E-14071 Córdoba, Spain.
María T Martín-RomeroDepartamento de Química Física y T. Aplicada, Instituto Químico para la Energía y Medioambiente IQUEMA, Facultad de Ciencias, Universidad de Córdoba, Campus de Rabanales, Ed. Marie Curie, E-14071 Córdoba, Spain.
Luis CamachoDepartamento de Química Física y T. Aplicada, Instituto Químico para la Energía y Medioambiente IQUEMA, Facultad de Ciencias, Universidad de Córdoba, Campus de Rabanales, Ed. Marie Curie, E-14071 Córdoba, Spain.ORCID 0000-0002-2141-1437
Juan M CuervaDepartamento de Química Orgánica, Facultad de Ciencias, Unidad de Excelencia Química Aplicada a Biomedicina y Medioambiente, Universidad de Granada, Avda. Fuente Nueva, s/n, 18071 Granada, Spain.ORCID 0000-0001-6896-9617
Victor BlancoDepartamento de Química Orgánica, Facultad de Ciencias, Unidad de Excelencia Química Aplicada a Biomedicina y Medioambiente, Universidad de Granada, Avda. Fuente Nueva, s/n, 18071 Granada, Spain.ORCID 0000-0002-6809-079X
Juan J Giner-CasaresDepartamento de Química Física y T. Aplicada, Instituto Químico para la Energía y Medioambiente IQUEMA, Facultad de Ciencias, Universidad de Córdoba, Campus de Rabanales, Ed. Marie Curie, E-14071 Córdoba, Spain.ORCID 0000-0002-6673-300X
Luis Álvarez de CienfuegosDepartamento de Química Orgánica, Facultad de Ciencias, Unidad de Excelencia Química Aplicada a Biomedicina y Medioambiente, Universidad de Granada, Avda. Fuente Nueva, s/n, 18071 Granada, Spain.ORCID 0000-0001-8910-4241
Araceli G CampañaDepartamento de Química Orgánica, Facultad de Ciencias, Unidad de Excelencia Química Aplicada a Biomedicina y Medioambiente, Universidad de Granada, Avda. Fuente Nueva, s/n, 18071 Granada, Spain.ORCID 0000-0001-5483-5642
Universidad de Granada · ESUniversity of Córdoba · ES

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We report the synthesis of a new set of amphiphilic saddle-shaped heptagon-containing polycyclic aromatic hydrocarbons (PAHs) functionalized with tetraethylene glycol chains and their self-assembly into large two-dimensional (2D) polymers. An in-depth analysis of the self-assembly mechanism at the air/water interface has been carried out, and the proposed arrangement models are in good agreement with the molecular dynamics simulations. Quite remarkably, the number and disposition of the tetraethylene glycol chains significantly influence the disposition of the PAHs at the interface and conditionate their packing under pressure. For the three compounds studied, we observed three different behaviors in which the aromatic core is parallel, perpendicular, and tilted with respect to the water surface. We also show that these curved PAHs are able to self-assemble in solution into remarkably large sheets of up to 150 μm

Identifiers

PMID38087461
PMCPMC10777395
OpenAlexW4389679766

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.