ArticleJournal of the American Chemical Society2023
Ni-Catalyzed 1,1- and 1,3-Aminoboration of Unactivated Alkenes.
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
4 citing papers in PubMed.
- Scope and Limitations of the PdClThe Journal of organic chemistry · 2026Article
- Diastereo- and enantioselective 1,3-hydrofunctionalization of trisubstituted alkenes by a directing relay.Nature chemistry · 2026Article
- Pd- and Cu-Cocatalyzed Anaerobic Olefin Aminoboration.The Journal of organic chemistry · 2025Article
- Diverse Synthesis of C-Glycosides by Stereoselective Ni-Catalyzed Carboboration of Glycals.Journal of the American Chemical Society · 2024Article
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Authors and funding
4 authors.
Funding
Abstract
Alkene borylfunctionalization reactions have emerged as useful methods for chemical synthesis. While much progress has been made on 1,2-borylamination reactions, the related 1,1- and 1,3-borylaminations have not been reported. Herein, a Ni-catalyzed 1,1-borylamination of 1,1-disubstituted and monosubstituted alkenes and a 1,3-borylamination of cyclic alkenes are presented. Key to development of these reactions was the identification of an alkyllithium activator in combination with Mg salts. The utility of the products and the mechanistic details are discussed.
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Registered trials
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