ReviewProceedings of the Japan Academy. Series B, Physical and biological sciences2023
Recent progress in the chemistry of heavy aromatics.
Review in Proceedings of the Japan Academy. Series B, Physical and biological sciences, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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2 citing papers in PubMed.
- 1,3-Disilabicyclo[1.1.0]butane and ηInorganic chemistry · 2026Article
- Conjugated Inorganic-Organic Hybrid Polymers with p-Block Elements.Angewandte Chemie (International ed. in English) · 2026Review
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3 authors.
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Abstract
The aromaticity and synthetic application of "heavy benzenes", i.e., benzenes containing a heavier Group 14 element (Si, Ge, Sn, and Pb) in place of skeletal carbon, have been the targets of many theoretical and synthetic studies. Although the introduction of a sterically demanding substituent enabled us to synthesize and isolate heavy aromatic species as a stable compound by suppressing their high reactivity and tendency to polymerize, the existence of a protection group is an obstruction to the development of functional materials based on heavy aromatics. This review will delineate the most recent topics in the chemistry of heavy aromatics, i.e., the chemistry of "metallabenzenyl anions", which are the heavier Group 14 element analogs of phenyl anions stabilized by taking advantage of charge repulsion instead of steric protection.
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