ArticleNature chemistry2024
Air- and photo-stable luminescent carbodicarbene-azaboraacenium ions.
Article in Nature chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Emissive BN-Embedded Cumulenes: Synthesis and Bidirectional Photocurrent Modulation.Angewandte Chemie (International ed. in English) · 2026Article
- Donor-Acceptor Pentacene Analogues With Near-Infrared Emission and Tunable Aromaticity.Angewandte Chemie (International ed. in English) · 2026Article
- Diboron- and digermanium-doped dihydrodibenzohexacenes: Ge-B exchange to access boron-doped extended acenes.Chemical science · 2026Article
- Unlocking red-to-near-infrared luminescence via ion-pair assembly in carbodicarbene borenium ions.Nature chemistry · 2026Article
- Iridium-Catalyzed Twofold C-H/C-H Activation and Annulation: Access to Anti-Kasha Emission and Photosensitive-Phosphorescent Materials.Journal of the American Chemical Society · 2025Article
- Conversion of Bestmann Ylide into Carbophosphinocarbene.Angewandte Chemie (International ed. in English) · 2025Article
- B ← N Lewis Pair Fusion of N,N-Diaryldihydrophenazines: Effect on Structural, Electronic, and Emissive Properties.Angewandte Chemie (International ed. in English) · 2025Article
- Synthesis of strained, air-stable boracycles via boron-carbon-centred diradicals.Nature chemistry · 2025Article
- Phosphine→Borane-Functionalized Pyrenes and Anthracenes.Angewandte Chemie (International ed. in English) · 2025Article
- Catalytic insertion of nitrenes into B-H bonds.Chemical science · 2025Article
- Optimal Synergy between Azulenes and Acenes in Azuacenes with 6-7-5 Ring Topology.Journal of the American Chemical Society · 2025Article
- Organic Room Temperature Phosphorescence from BN-Substituted Xanthene Derivatives.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
6 authors.
Funding
Abstract
Substitution of a C=C bond by an isoelectronic B-N bond is a well-established strategy to alter the electronic structure and stability of acenes. BN-substituted acenes that possess narrow energy gaps have attractive optoelectronic properties. However, they are susceptible to air and/or light. Here we present the design, synthesis and molecular structures of fully π-conjugated cationic BN-doped acenes stabilized by carbodicarbene ligands. They are luminescent in the solution and solid states and show high air and moisture stability. Compared with their neutral BN-substituted counterparts as well as the parent all-carbon acenes, these species display improved quantum yields and small optical gaps. The electronic structures of the azabora-anthracene and azabora-tetracene cations resemble higher-order acenes while possessing high photo-oxidative resistance. Investigations using density functional theory suggest that the stability and photo-physics of these conjugated systems may be ascribed to their cationic nature and the electronic properties of the carbodicarbene.
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Registered trials
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