Evidence map›Paper›PMID 38052925›Full record

ArticleCommunications chemistry2023

Migration and aggregation of Pt atoms on metal oxide-supported ceria nanodomes control reverse water gas shift reaction activity.

Haodong Wang, Ryuichi Shimogawa, Lihua Zhang, Lu Ma, Steven N Ehrlich, Nebojsa Marinkovic, Yuanyuan Li, Anatoly I Frenkel

Abstract read
In one paragraph

Article in Communications chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. CO Adsorption on a Single-Atom Catalyst Stably Embedded in Graphene.Angewandte Chemie (International ed. in English) · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Haodong WangDepartment of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY, 11794, USA.
Ryuichi ShimogawaDepartment of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY, 11794, USA.
Lihua ZhangCenter for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY, 11973, USA.
Lu MaNational Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, 11973, USA.
Steven N EhrlichNational Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, 11973, USA.
Nebojsa MarinkovicDepartment of Chemical Engineering, Columbia University, New York, NY, 10027, USA.ORCID http://orcid.org/0000-0003-3579-3453
Yuanyuan LiChemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA. liy4@ornl.gov.ORCID http://orcid.org/0000-0003-3074-9672
Anatoly I FrenkelDepartment of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY, 11794, USA. anatoly.frenkel@stonybrook.edu.ORCID http://orcid.org/0000-0002-5451-1207

Funding

DOE | SC | Basic Energy Sciences (BES) DE-SC0022199
6 · The paper itself

Abstract

Single-atom catalysts (SACs) are particularly sensitive to external conditions, complicating the identification of catalytically active species and active sites under in situ or operando conditions. We developed a methodology for tracing the structural evolution of SACs to nanoparticles, identifying the active species and their link to the catalytic activity for the reverse water gas shift (RWGS) reaction. The new method is illustrated by studying structure-activity relationships in two materials containing Pt SACs on ceria nanodomes, supported on either ceria or titania. These materials exhibited distinctly different activities for CO production. Multimodal operando characterization attributed the enhanced activity of the titania-supported catalysts at temperatures below 320 ˚C to the formation of unique Pt sites at the ceria-titania interface capable of forming Pt nanoparticles, the active species for the RWGS reaction. Migration of Pt nanoparticles to titania support was found to be responsible for the deactivation of titania-supported catalysts at elevated temperatures. Tracking the migration of Pt atoms provides a new opportunity to investigate the activation and deactivation of Pt SACs for the RWGS reaction.

Identifiers

PMID38052925
PMCPMC10697936

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.