Evidence map›Paper›PMID 38051226›Full record

ArticleChemical communications (Cambridge, England)2023

Chemo- and enantioselective intramolecular silver-catalyzed aziridinations of carbamimidates.

Tuan Anh Trinh, Yue Fu, Derek B Hu, Soren A Zappia, Ilia A Guzei, Peng Liu, Jennifer M Schomaker

Open access · greenAbstract read
In one paragraph

Article in Chemical communications (Cambridge, England), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
1.6field-weighted citation impact, top 17% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed, 11 citations in OpenAlex.

  1. Article
  2. Article
  3. Recent Developments in Catalytic Asymmetric Aziridination.Topics in current chemistry (Cham) · 2025
    Review
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 2 institutions in 1 country.

Tuan Anh TrinhDepartment of Chemistry, University of Wisconsin, 1101 University Avenue, Madison WI 53706, USA. schomakerj@chem.wisc.edu.ORCID http://orcid.org/0000-0003-3487-2483
Yue FuDepartment of Chemistry, University of Pittsburgh, 219 Parkman Ave, Pittsburgh, PA 15260, USA.ORCID http://orcid.org/0000-0003-3085-7817
Derek B HuDepartment of Chemistry, University of Wisconsin, 1101 University Avenue, Madison WI 53706, USA. schomakerj@chem.wisc.edu.
Soren A ZappiaDepartment of Chemistry, University of Wisconsin, 1101 University Avenue, Madison WI 53706, USA. schomakerj@chem.wisc.edu.
Ilia A GuzeiDepartment of Chemistry, University of Wisconsin, 1101 University Avenue, Madison WI 53706, USA. schomakerj@chem.wisc.edu.
Peng LiuDepartment of Chemistry, University of Pittsburgh, 219 Parkman Ave, Pittsburgh, PA 15260, USA.ORCID http://orcid.org/0000-0002-8188-632X
Jennifer M SchomakerDepartment of Chemistry, University of Wisconsin, 1101 University Avenue, Madison WI 53706, USA. schomakerj@chem.wisc.edu.ORCID http://orcid.org/0000-0003-1329-950X
University of Wisconsin–Madison · USUniversity of Pittsburgh · US

Funding

Computational Models for Reactivity and Selectivity in Transition Metal-Catalyzed Olefin FunctionalizationR35GM128779 · NIGMS · UNIVERSITY OF PITTSBURGH AT PITTSBURGH · PI Peng Liu · 2018 to 2026
$2.9M
QExactive (Orbitrap) mass spectrometerS10OD020022 · OD · UNIVERSITY OF WISCONSIN-MADISON · PI VESTLING, MARTHA M · 2015 to 2015
$483k
NMR SPECTROMETERS10RR008389 · NCRR · UNIVERSITY OF WISCONSIN MADISON · PI VEDEJS, EDWIN · 1993 to 1993
–
NCRR NIH HHS S10 RR008389NIGMS NIH HHS R35 GM128779NIH HHS S10 OD020022
6 · The paper itself

Abstract

Transition metal-catalyzed asymmetric nitrene transfer is a powerful method to generate enantioenriched amines found in natural products and bioactive molecules. A highly chemo- and enantioselective intramolecular silver-catalysed aziridination of 2,2,2-trichloroethoxysulfonyl (Tces)-protected carbamimidates gives [4.1.0]-bicyclic aziridines in good yields and up to 99% ee.

Identifiers

PMID38051226
PMCPMC11788935
OpenAlexW4389185486

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.