Evidence map›Paper›PMID 38047620›Full record

ArticleJournal of the American Chemical Society2023

The Role of Surface Complexes in Ketene Formation from Fatty Acids via Pyrolysis over Silica: from Platform Molecules to Waste Biomass.

Liana R Azizova, Tetiana V Kulik, Borys B Palianytsia, Mykola M Ilchenko, German M Telbiz, Alina M Balu, Sergiy Tarnavskiy, Rafael Luque, Alberto Roldan, Mykola T Kartel

Open access · hybridAbstract read
In one paragraph

Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
1.0field-weighted citation impact, top 27% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 9 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors at 6 institutions in 5 countries.

Liana R AzizovaSchool of Dentistry, Cardiff University, Heath Park, Cardiff CF14 4XY, U.K.ORCID 0000-0001-7096-4452
Tetiana V KulikChuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, Kyiv 03164, Ukraine.ORCID 0000-0002-1740-0348
Borys B PalianytsiaChuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, Kyiv 03164, Ukraine.ORCID 0000-0002-6676-632X
Mykola M IlchenkoInstitute of Molecular Biology and Genetics, National Academy of Science of Ukraine, 150 Zabolotnogo Str., Kyiv 03680, Ukraine.
German M TelbizNational Academy of Science of Ukraine, L. V. Pisarzhevsky Institute of Physical Chemistry, Nauky Av. 31, Kyiv 03039, Ukraine.
Alina M BaluDepartamento de Química Orgánica, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie (C-3), Ctra Nnal IV-A, Km 396, Cordoba E14014, Spain.
Sergiy TarnavskiyInstitute of Molecular Biology and Genetics, National Academy of Science of Ukraine, 150 Zabolotnogo Str., Kyiv 03680, Ukraine.
Rafael LuqueUniversitá degli studi Mediterranea di Reggio Calabria (UNIRC), DICEAM, Via Zehender (giá via Graziella), Loc. Feo di Vito, I89122 Reggio Calabria, Italy.ORCID 0000-0003-4190-1916
Alberto RoldanCardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, U.K.ORCID 0000-0003-0353-9004
Mykola T KartelChuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, Kyiv 03164, Ukraine.
Chuiko Institute of Surface Chemistry · UAInstitute of Molecular Biology and Genetics · UACardiff University · GBL.V. Pisarzhevskii Institute of Physical Chemistry · UAUniversidad Ecotec · ECUniversity of Córdoba · ES

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Fatty acids (FA) are the main constituents of lipids and oil crop waste, considered to be a promising 2G biomass that can be converted into ketenes via catalytic pyrolysis. Ketenes are appraised as promising synthons for the pharmaceutical, polymer, and chemical industries. Progress in the thermal conversion of short- and long-chain fatty acids into ketenes requires a deep understanding of their interaction mechanisms with the nanoscale oxide catalysts. In this work, the interactions of fatty acids with silica are investigated using a wide range of experimental and computational techniques (TPD MS, DFT, FTIR,

Identifiers

PMID38047620
PMCPMC10722514
OpenAlexW4389298837

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.