ReviewOrganic & biomolecular chemistry2023
Cu(II) salts as terminal oxidants in visible-light photochemical oxidation reactions.
Review in Organic & biomolecular chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
4 citing papers in PubMed, 6 citations in OpenAlex.
- Formal Hydride Abstraction: A Unified Photoredox Platform for Nucleophilic C(sp3)-H Functionalization.Accounts of chemical research · 2026Article
- Harnessing Photochemistry in Natural Product Synthesis: From Strategy to Applications.Journal of natural products · 2025Review
- Preassembly-Controlled Radical Recombination at Bismuth: Decarboxylative C─N Coupling with Sulfonamides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Chiral pyrrolidines via an enantioselective Hofmann-Löffler-Freytag reaction.Chem catalysis · 2024Article
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
Photochemistry provides an important platform for the discovery of synthetically useful transformations. The development of new oxidative photoreactions, however, has proven to be relatively challenging. The importance of the identity of the terminal oxidant has been an underappreciated consideration in the design of these reactions. Many of the most common terminal oxidants used in ground-state catalytic methods are poorly compatible with the one-electron oxidation state changes characteristic of photoredox reactions and result in hard-to-control deleterious side reactions. As an alternative, Cu(II) salts have emerged as versatile terminal oxidants in photochemical oxidation reactions that are terrestrially abundant, cost-effective, and readily compatible with one-electron oxidation state changes. This review highlights recent reaction methods that leverage Cu(II) oxidation in combination with the photochemical activation of substrates or that use Cu(II) salts as both the active chromophore and terminal oxidant.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.