Experimental and

Pristine ZnO and Co-doped ZnO photocatalyst thin films were fabricated on a ceramic substrate by spray pyrolysis. The optical, morphological and structural properties of the fabricated nanophotocatalyst thin films were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy and Fourier transform infrared (FTIR) spectroscopy. Operational parameters, including dye concentration, oxidant concentration, irradiation time and pH for dye degradation, were optimized by response surface methodology (RSM). The maximum degradation obtained was 93% under ideal conditions, such as pH 7, 3 h of direct sunlight irradiation, 30 mM concentration of oxidant and 10 ppm concentration of dye (MB). The evaluation of the extent of degradation was done using the UV/visible spectrophotometry technique. The reusability of the fabricated thin film was examined under optimized conditions. Density functional theory (DFT) with the B3LYP/LanL2DZ method was used for the theoretical modelling of the fabricated nanomaterials. The optimized structure, theoretical band gaps, IR spectra and Raman spectra of the fabricated pristine ZnO and Co:ZnO nanophotocatalysts were determined.