Evidence map›Paper›PMID 38031591›Full record

ArticleOrganometallics2022

Pd-PEPPSI N-Heterocyclic Carbene Complexes from Caffeine: Application in Suzuki, Heck, and Sonogashira Reactions.

Md Mahbubur Rahman, Jin Zhang, Qun Zhao, Jessica Feliciano, Elwira Bisz, Błażej Dziuk, Roger Lalancette, Roman Szostak, Michal Szostak

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Organometallics, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Crystal structure ofActa crystallographica. Section E, Crystallographic communications · 2026
    Article
  2. Review
  3. IPrOrganometallics · 2024
    Article
  4. Review
  5. Article
  6. [Au(NpCatalysis science & technology · 2023
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Md Mahbubur RahmanDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, New Jersey 07102, United States.
Jin ZhangCollege of Chemistry and Chemical Engineering, Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi University of Science and Technology, Xi'an 710021, China.
Qun ZhaoDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, New Jersey 07102, United States.
Jessica FelicianoDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, New Jersey 07102, United States.
Elwira BiszDepartment of Chemistry, Opole University, 48 Oleska Street, Opole 45-052, Poland.
Błażej DziukDepartment of Chemistry, University of Science and Technology, Norwida 4/6, Wroclaw 50-373, Poland.
Roger LalancetteDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, New Jersey 07102, United States.
Roman SzostakDepartment of Chemistry, Wroclaw University, F. Joliot-Curie 14, Wroclaw 50-383, Poland.
Michal SzostakDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, New Jersey 07102, United States.

Funding

Catalytic Methods for Organic SynthesisR35GM133326 · NIGMS · RUTGERS THE STATE UNIV OF NJ NEWARK · PI Michal Szostak · 2019 to 2026
$2.7M
NIGMS NIH HHS R35 GM133326
6 · The paper itself

Abstract

The first synthesis of Pd-PEPPSI N-heterocyclic carbene complexes derived from the abundant and renewable natural product caffeine is reported. The catalysts bearing 3-chloro-pyridine, pyridine and N-methylimidazole ancillary ligands were readily prepared from the corresponding N9-Me caffeine imidazolium salt by direct deprotonation and coordination to PdX

Identifiers

PMID38031591
PMCPMC10686539

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.