Evidence map›Paper›PMID 38023516›Full record

ArticleChemical science2023

Halogen bonding with carbon: directional assembly of non-derivatised aromatic carbon systems into robust supramolecular ladder architectures.

Jogirdas Vainauskas, Tristan H Borchers, Mihails Arhangelskis, Laura J McCormick McPherson, Toni S Spilfogel, Ehsan Hamzehpoor, Filip Topić, Simon J Coles, Dmytro F Perepichka, Christopher J Barrett and 1 more

Abstract read
In one paragraph

Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Redox-Active Ligands Permit Multielectron OJournal of the American Chemical Society · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Jogirdas VainauskasSchool of Chemistry, University of Birmingham Edgbaston Birmingham B15 2TT UK t.friscic@bham.ac.uk.ORCID https://orcid.org/0000-0001-7060-0931
Tristan H BorchersSchool of Chemistry, University of Birmingham Edgbaston Birmingham B15 2TT UK t.friscic@bham.ac.uk.
Mihails ArhangelskisFaculty of Chemistry, University of Warsaw 1 Pasteura Street Warsaw 02-093 Poland.ORCID https://orcid.org/0000-0003-1150-3108
Laura J McCormick McPhersonEPSRC National Crystallography Service, School of Chemistry, University of Southampton, Highfield Southampton UK.ORCID https://orcid.org/0000-0002-6634-4717
Toni S SpilfogelDepartment of Chemistry, McGill University 801 Sherbrooke St. W. H3A 0B8 Montreal Canada.
Ehsan HamzehpoorDepartment of Chemistry, McGill University 801 Sherbrooke St. W. H3A 0B8 Montreal Canada.ORCID https://orcid.org/0000-0002-5427-9444
Filip TopićDepartment of Chemistry, McGill University 801 Sherbrooke St. W. H3A 0B8 Montreal Canada.ORCID https://orcid.org/0000-0003-3811-6036
Simon J ColesEPSRC National Crystallography Service, School of Chemistry, University of Southampton, Highfield Southampton UK.ORCID https://orcid.org/0000-0001-8414-9272
Dmytro F PerepichkaDepartment of Chemistry, McGill University 801 Sherbrooke St. W. H3A 0B8 Montreal Canada.ORCID https://orcid.org/0000-0003-2233-416X
Christopher J BarrettDepartment of Chemistry, McGill University 801 Sherbrooke St. W. H3A 0B8 Montreal Canada.ORCID https://orcid.org/0000-0001-6194-9066
Tomislav FriščićSchool of Chemistry, University of Birmingham Edgbaston Birmingham B15 2TT UK t.friscic@bham.ac.uk.ORCID https://orcid.org/0000-0002-3921-7915

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Carbon, although the central element in organic chemistry, has been traditionally neglected as a target for directional supramolecular interactions. The design of supramolecular structures involving carbon-rich molecules, such as arene hydrocarbons, has been limited almost exclusively to non-directional π-stacking, or derivatisation with heteroatoms to introduce molecular assembly recognition sites. As a result, the predictable assembly of non-derivatised, carbon-only π-systems using directional non-covalent interactions remains an unsolved fundamental challenge of solid-state supramolecular chemistry. Here, we propose and validate a different paradigm for the reliable assembly of carbon-only aromatic systems into predictable supramolecular architectures: not through non-directional π-stacking, but

Identifiers

PMID38023516
PMCPMC10664517

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.