Evidence map›Paper›PMID 38009850›Full record

ArticleOrganic letters2023

Organocatalytic Michael Addition of Unactivated α-Branched Nitroalkanes to Afford Optically Active Tertiary Nitrocompounds.

Beñat Lorea, Ane García-Urricelqui, José M Odriozola, Jesús Razkin, Maialen Espinal-Viguri, Mikel Oiarbide, Antonia Mielgo, Jesús M García, Claudio Palomo

Abstract read
In one paragraph

Article in Organic letters, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Beñat LoreaDepartamento de Ciencias, Institute for Advanced Materials and Mathematics (InaMat2), Universidad Pública de Navarra (UPNA), 31006 Pamplona, Spain.
Ane García-UrricelquiDepartamento de Química Orgánica I, Universidad del País Vasco UPV/EHU, Manuel Lardizábal 3, 20018 San Sebastián, Spain.
José M OdriozolaDepartamento de Ciencias, Institute for Advanced Materials and Mathematics (InaMat2), Universidad Pública de Navarra (UPNA), 31006 Pamplona, Spain.
Jesús RazkinDepartamento de Ciencias, Institute for Advanced Materials and Mathematics (InaMat2), Universidad Pública de Navarra (UPNA), 31006 Pamplona, Spain.
Maialen Espinal-ViguriDepartamento de Ciencias, Institute for Advanced Materials and Mathematics (InaMat2), Universidad Pública de Navarra (UPNA), 31006 Pamplona, Spain.
Mikel OiarbideDepartamento de Química Orgánica I, Universidad del País Vasco UPV/EHU, Manuel Lardizábal 3, 20018 San Sebastián, Spain.ORCID 0000-0003-0362-0136
Antonia MielgoDepartamento de Química Orgánica I, Universidad del País Vasco UPV/EHU, Manuel Lardizábal 3, 20018 San Sebastián, Spain.ORCID 0000-0001-8197-017X
Jesús M GarcíaDepartamento de Ciencias, Institute for Advanced Materials and Mathematics (InaMat2), Universidad Pública de Navarra (UPNA), 31006 Pamplona, Spain.ORCID 0000-0001-6632-097X
Claudio PalomoDepartamento de Química Orgánica I, Universidad del País Vasco UPV/EHU, Manuel Lardizábal 3, 20018 San Sebastián, Spain.ORCID 0000-0001-9809-2799

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The direct, asymmetric conjugate addition of unactivated α-branched nitroalkanes is developed based on the combined use of chiral amine/ureidoaminal bifunctional catalysts and a tunable acrylate template to provide tertiary nitrocompounds in 55-80% isolated yields and high enantioselectivity (

Identifiers

PMID38009850
PMCPMC10714440

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.