ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2024
Complexes of N-Confused Porphyrin Derivatives as Ortho-Metallating Ligands. Synthesis, Structure, Redox Properties, and Chirality.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Oxygenated N-Confused Porphyrins: Structural Elucidation and Distinct Vanadium(IV) Coordination Motifs.Inorganic chemistry · 2026Article
- Pyridine-Fused Bis(azacorrole)s: Easily Accessible NIR III Absorbing Cation Radicals and Biradicaloids of Antiaromatic Ground State.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Complexes of N-Confused Porphyrin Derivatives as Ortho-Metallating Ligands. Synthesis, Structure, Redox Properties, and Chirality.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
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Authors and funding
5 authors.
Funding
Abstract
A family of transition metal complexes of meso-aryl-2-aza-21-carbaporphyrin (N-confused porphyrin, NCP) derivatives acting as ortho-metallating ligands for ruthenium(II), rhodium(III), and iridium(III) is synthesized and characterized by XRD, spectroscopic, and electrochemical methods. The chirality of these systems is shown by the separation of the enantiomers and analyzed by circular dichroism and DFT. A preliminary catalytic study indicates the activity of the iridium(III) ortho-metallated complexes in the N-heterocyclization of primary amines with diols.
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