ArticleJournal of the American Chemical Society2023
Highly Conductive Topologically Chiral Molecular Knots as Efficient Spin Filters.
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Circularly polarized electroluminescence from topologically chiral [2]catenane-based neutral radicals with tunable deep-red emission.Nature communications · 2026Article
- Stereoselective Synthesis of Topologically Chiral Knots and Links: Synthesis and Applications.Molecules (Basel, Switzerland) · 2026Review
- Chirobiophore: A Novel Framework for Quantifying Biochirality in Macromolecular Systems.Biomolecules · 2026Article
- Robust chirality-induced spin selectivity in topologically chiral molecular knots.Nature communications · 2025Article
- Observation of Near-Infrared Photothermal and Photoacoustic Effects in a Metallosupramolecular Trefoil Knot.Angewandte Chemie (International ed. in English) · 2025Article
- Chiral two-dimensional conjugated metal-organic frameworks with high spin polarization.Nature communications · 2025Article
- Decoding information stored in DNAs through single-molecule electrical detection platforms.Innovation (Cambridge (Mass.)) · 2025Review
- Chiral Induced Spin Polarized Electron Current: Origin of the Chiral Induced Spin Selectivity Effect.The journal of physical chemistry letters · 2025Article
- Homochiral Carboxylate-Anchored Truxene Tripods: Design, Synthesis, and Monolayer Formation on Ag(111).Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Artificial light harvesting systems based on novel AIEgen-branched rotaxane dendrimers for photocatalyzed functionalization of C-H bonds.Chemical science · 2025Article
- The chirality-induced spin selectivity effect in asymmetric spin transport: from solution to device applications.Chemical science · 2024Review
- Folding a Molecular Strand into a Trefoil Knot of Single Handedness with Co(II)/Co(III) Chaperones.Journal of the American Chemical Society · 2024Article
- Atroposelective Formal [2 + 5] Macrocyclization Synthesis for a Novel All-Hydrocarbon Cyclo[7]Molecules (Basel, Switzerland) · 2024Article
- Spin polarized current in chiral organic radical monolayers.Journal of materials chemistry. C · 2024Article
- Effect of Bridging Manner on the Transport Behaviors of Dimethyldihydropyrene/Cyclophanediene Molecular Devices.Molecules (Basel, Switzerland) · 2024Article
- Tuning vibration-induced emission through macrocyclization and catenation.Chemical science · 2024Article
- Mechanism for Electrostatically Generated Magnetoresistance in Chiral Systems without Spin-Dependent Transport.ACS nano · 2024Review
- Amino Turbo Chirality and Its Asymmetric Control.Research (Washington, D.C.) · 2024Article
Corrections and comments
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Knot-like structures were found to have interesting magnetic properties in condensed matter physics. Herein, we report on topologically chiral molecular knots as efficient spintronic chiral material. The discovery of the chiral-induced spin selectivity (CISS) effect opens the possibility of manipulating the spin orientation with soft materials at room temperature and eliminating the need for a ferromagnetic electrode. In the chiral molecular trefoil knot, there are no stereogenic carbon atoms, and chirality results from the spatial arrangements of crossings in the trefoil knot structures. The molecules show a very high spin polarization of nearly 90%, a conductivity that is higher by about 2 orders of magnitude compared with that of other chiral small molecules, and enhanced thermal stability. A plausible explanation for these special properties is provided, combined with model calculations, that supports the role of electron-electron interaction in these systems.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.