ArticleMolecules (Basel, Switzerland)2023
An Unusual Rearrangement of Pyrazole Nitrene and Coarctate Ring-Opening/Recyclization Cascade: Formal CH-Acetoxylation and Azide/Amine Conversion without External Oxidants and Reductants.
Elena Chugunova, Almir S Gazizov, Daut Islamov, Victoria Matveeva, Alexander Burilov, Nurgali Akylbekov, Alexey Dobrynin, Rakhmetulla Zhapparbergenov, Nurbol Appazov, Beauty K Chabuka and 3 more
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In one paragraphArticle in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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5 · Who and what moneyAuthors and funding
13 authors.
Elena ChugunovaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Akad. Arbuzov St. 8, Kazan 420088, Russia.ORCID 0000-0002-9371-1877 Almir S GazizovArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Akad. Arbuzov St. 8, Kazan 420088, Russia.ORCID 0000-0001-9899-9606 Daut IslamovArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Akad. Arbuzov St. 8, Kazan 420088, Russia.
Victoria MatveevaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Akad. Arbuzov St. 8, Kazan 420088, Russia.
Alexander BurilovArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Akad. Arbuzov St. 8, Kazan 420088, Russia.
Nurgali AkylbekovLaboratory of Engineering Profile "Physical and Chemical Methods of Analysis", Korkyt Ata Kyzylorda University, Aitekebie Str. 29A, Kyzylorda 120014, Kazakhstan.ORCID 0000-0002-7584-9741 Alexey DobryninArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Akad. Arbuzov St. 8, Kazan 420088, Russia.
Rakhmetulla ZhapparbergenovLaboratory of Engineering Profile "Physical and Chemical Methods of Analysis", Korkyt Ata Kyzylorda University, Aitekebie Str. 29A, Kyzylorda 120014, Kazakhstan.
Nurbol AppazovLaboratory of Engineering Profile "Physical and Chemical Methods of Analysis", Korkyt Ata Kyzylorda University, Aitekebie Str. 29A, Kyzylorda 120014, Kazakhstan.ORCID 0000-0001-8765-3386 Beauty K ChabukaDepartment of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, FL 32306-3290, USA.ORCID 0000-0001-5332-2415 Kimberley ChristopherDepartment of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, FL 32306-3290, USA.
Daria I TonkoglazovaDepartment of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, FL 32306-3290, USA.
Igor V AlabuginArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Akad. Arbuzov St. 8, Kazan 420088, Russia.ORCID 0000-0001-9289-3819 Funding
the Ministry of Science and Higher Education of the Russian Federation at FRC Kazan Scientific Center 075-15-2022-1128the Science Committee of the Ministry of Science and Higher Education of the Republic of Kazakhstan AP19677249
6 · The paper itselfAbstract
We report an unusual transformation where the transient formation of a nitrene moiety initiates a sequence of steps leading to remote oxidative C-H functionalization (R-CH
Indexed as
1H-pyrazolecyclizationfragmentationfuroxannitrene
Identifiers
PMID37959754
PMCPMC10648078
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