Evidence map›Paper›PMID 37956247›Full record

ArticleAnalytical chemistry2023

Theoretical Framework and Guidelines for the Cyclic Voltammetry of Closed Bipolar Cells.

Eduardo Laborda, Javier López-Asanza, Angela Molina

Abstract read
In one paragraph

Article in Analytical chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Eduardo LabordaDepartamento de Química Física, Facultad de Química, Regional Campus of International Excellence "Campus Mare Nostrum", Universidad de Murcia, 30100 Murcia, Spain.ORCID 0000-0002-2997-4066
Javier López-AsanzaDepartamento de Química Física, Facultad de Química, Regional Campus of International Excellence "Campus Mare Nostrum", Universidad de Murcia, 30100 Murcia, Spain.
Angela MolinaDepartamento de Química Física, Facultad de Química, Regional Campus of International Excellence "Campus Mare Nostrum", Universidad de Murcia, 30100 Murcia, Spain.ORCID 0000-0002-9661-1660

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Closed bipolar cells (cBPCs) can offer valuable platforms for the development of electrochemical sensors. On the other hand, such systems are more intricate to model and interpret than conventional systems with a single polarizable interface, with the applied potential "splitting" into two polarized interfaces where two coupled charge transfers take place concomitantly. As a result, the voltammetry of cBPCs shows peculiarities that can be misleading if analyzed under the framework of classic electrochemical cells. In this work, rigorous mathematical solutions are deduced for the cyclic voltammetry (CV) of cBPCs, including the current-potential response, the interfacial potentials, and the interfacial redox concentrations. With such theoretical tools, a comprehensive view of the behavior of cBPCs can be gained, and adequate diagnosis criteria are established on the basis of the shape, magnitude, and position of the CV signal as a function of the scan rate and of the experimental conditions in the anodic and cathodic compartments.

Identifiers

PMID37956247
PMCPMC10688229

What OpenQuestion holds

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LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.