ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2024
Photochemical Action Plots Reveal the Fundamental Mismatch Between Absorptivity and Photochemical Reactivity.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
28 citing papers in PubMed.
- Chlorine-Free Depolymerization of Commercial PMMA via Oxygen-Centered Radicals.Angewandte Chemie (International ed. in English) · 2026Article
- Toward Chromoselective Transformations in Biological Systems: Perspectives and Challenges.Angewandte Chemie (International ed. in English) · 2026Review
- Novel Non-Cytotoxic Acylphosphinates and Acylphosphine Oxides Photoinitiators.Angewandte Chemie (International ed. in English) · 2026Article
- Mixed-Functionalized Acylgermanes Result in Wavelength-Controlled Fragmentation.Angewandte Chemie (International ed. in English) · 2026Article
- Wavelength-Dependent 3D Printing: Introducing 3D Printed Action Plots.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Solar Flow Synthesis of Polymer Nanoparticles: Scaling Local Experiments to Global Potential.Angewandte Chemie (International ed. in English) · 2026Article
- Automated Plasmon-Selective Laser Writing in Mesoporous Thin Films Through Decoupling of the Initiator Absorption and Plasmon Wavelength.Small science · 2026Article
- Standardizing Depolymerization: Strategies and Performance Metrics.Precision chemistry · 2025Review
- Article
- Precision Photochemistry: Every Photon Counts.Angewandte Chemie (International ed. in English) · 2025Article
- Digital light processing of photoresponsive and programmable hydrogels.Science advances · 2025Article
- Phototransposition of Indazoles to Benzimidazoles: Tautomer-Dependent Reactivity, Wavelength Dependence, and Continuous Flow Studies.Angewandte Chemie (International ed. in English) · 2025Article
- Photoredox Catalysts Based on N-(Hexyl)benzothioxanthene-3,4-dicarboximide for Photopolymerization and 3D Printing Under Visible Light.Angewandte Chemie (International ed. in English) · 2025Article
- Introducing Photochemical Action Plots as a Tool for Unlocking On-Off Switchable Behavior in a Polymeric Eosin Y Photocatalyst.Angewandte Chemie (International ed. in English) · 2025Article
- Molecular Steganography Using Multistate Photoswitchable Hydrazones.Journal of the American Chemical Society · 2025Article
- RAFT with Light: A User Guide to Using Thiocarbonylthio Compounds in Photopolymerizations.ACS polymers Au · 2025Article
- Skeletal Editing Strategies Driven by Total Synthesis.Accounts of chemical research · 2025Article
- Enhancing the Photoswitching Properties ofJournal of the American Chemical Society · 2025Article
- Two Material Properties from One Wavelength-Orthogonal Photoresin Enabled by a Monochromatic Laser Integrated Stereolithographic Apparatus (Mono LISA).Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Switching Sides: Regiochemistry and Functionalization Dictate the Photoswitching Properties of Imines.Angewandte Chemie (International ed. in English) · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors.
Funding
Abstract
Over the last years, the authors' laboratory has employed monochromatic tuneable laser systems to reveal a fundamental mismatch between the absorptivity of a chromophore and its photochemical reactivity for the vast majority of covalent bond forming reactions as well as specific bond cleavage reactions. In the general chemistry community, however, the long-held assumption pervades that effective photochemical reactions are obtained in situations where there is strong overlap between the absorption spectrum and the excitation wavelength. The current Perspective illustrates that the absorption spectrum of a molecule only provides information about electronic excitations and remains entirely silent on other energy redistribution mechanisms that follow, which critically influence photochemical reactivity. Future avenues of enquiry on how action plots can be understood are proposed and the importance of action plots for tailoring photochemical applications with never-before-seen precision is explored.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.