ArticleChemical science2023
Engineering a molecular ruthenium catalyst into three-dimensional metal covalent organic frameworks for efficient water oxidation.
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed, 24 citations in OpenAlex.
- Covalent Organic Frameworks for Photocatalysis.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Identifying Bottlenecks in the Photocatalytic Oxygen Evolution Reaction with Covalent Organic Frameworks.Chemistry of materials : a publication of the American Chemical Society · 2025Article
- An Adaptive Palladium Single-Atom Catalyst Enabling Reactivity Switching between Borylation and C-C Coupling.Journal of the American Chemical Society · 2025Article
- Stabilization of Ni-containing Keggin-type polyoxometalates with variable oxidation states as novel catalysts for electrochemical water oxidation.Chemical science · 2024Article
Corrections and comments
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Authors and funding
6 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The water oxidation reaction plays an important role in clean energy conversion, utilization, and storage, but mimicking the oxygen-evolving complex of photosystem II for designing active and stable water oxidation catalysts (WOCs) is still an appealing challenge. Here, we innovatively engineered a molecular ruthenium WOC as a metal complex building unit to construct a series of three-dimensional metal covalent organic frameworks (3D MCOFs) for realizing efficient oxidation catalysis. The resultant MCOFs possessed rare 3D interlocking structures with inclined interpenetration of two-dimensional covalent rhombic nets, and the Ru sites were periodically arranged in the crystalline porous frameworks. Impressively, these MCOFs showed excellent performance towards water oxidation (the O
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