ArticleNano-micro letters2023
Green-Solvent Processed Blade-Coating Organic Solar Cells with an Efficiency Approaching 19% Enabled by Alkyl-Tailored Acceptors.
Article in Nano-micro letters, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Precise End-Group Conjugated-Site Isomerization of Wing-Typed Dimeric Acceptors Enables 20.32% Efficiency Organic Solar Cells.Angewandte Chemie (International ed. in English) · 2026Article
- Multiscale Manufacturing of Organic Electronic Materials.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- Hydrogen-Bonding Networks Enabled by Trace Water for Morphological Design in Ternary Organic Solar Cells.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Evolving Role of Conjugated Polymers in Nanoelectronics and Photonics.Nano-micro letters · 2025Review
- Triplet State Suppression for Energy Loss Reduction in 20% Nonhalogenated Solvent Processed Binary Organic Solar Cells.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Kinetics Manipulation Enabled by Solubility Control Toward 19% Organic Solar Cells via Compatible Air Coating.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Suppressed Degradation Process of PBDB-TF-T1:BTP-4F-12-Based Organic Solar Cells with Solid Additive Atums Green.ACS applied materials & interfaces · 2025Article
- Halogenated Dibenzo[f,h]quinoxaline Units Constructed 2D-Conjugated Guest Acceptors for 19% Efficiency Organic Solar Cells.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Polymer Fiber Rigid Network with High Glass Transition Temperature Reinforces Stability of Organic Photovoltaics.Nano-micro letters · 2024Article
- Step-by-Step Modulation of Crystalline Features and Exciton Kinetics for 19.2% Efficiency Ortho-Xylene Processed Organic Solar Cells.Nano-micro letters · 2023Article
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Authors and funding
26 authors.
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Abstract
Power-conversion-efficiencies (PCEs) of organic solar cells (OSCs) in laboratory, normally processed by spin-coating technology with toxic halogenated solvents, have reached over 19%. However, there is usually a marked PCE drop when the blade-coating and/or green-solvents toward large-scale printing are used instead, which hampers the practical development of OSCs. Here, a new series of N-alkyl-tailored small molecule acceptors named YR-SeNF with a same molecular main backbone are developed by combining selenium-fused central-core and naphthalene-fused end-group. Thanks to the N-alkyl engineering, NIR-absorbing YR-SeNF series show different crystallinity, packing patterns, and miscibility with polymeric donor. The studies exhibit that the molecular packing, crystallinity, and vertical distribution of active layer morphologies are well optimized by introducing newly designed guest acceptor associated with tailored N-alkyl chains, providing the improved charge transfer dynamics and stability for the PM6:L8-BO:YR-SeNF-based OSCs. As a result, a record-high PCE approaching 19% is achieved in the blade-coating OSCs fabricated from a green-solvent o-xylene with high-boiling point. Notably, ternary OSCs offer robust operating stability under maximum-power-point tracking and well-keep > 80% of the initial PCEs for even over 400 h. Our alkyl-tailored guest acceptor strategy provides a unique approach to develop green-solvent and blade-coating processed high-efficiency and operating stable OSCs, which paves a way for industrial development.
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