Evidence map›Paper›PMID 37905554›Full record

ReviewChemical Society reviews2023

Visible light-responsive materials: the (photo)chemistry and applications of donor-acceptor Stenhouse adducts in polymer science.

Michèle Clerc, Sara Sandlass, Omar Rifaie-Graham, Julie A Peterson, Nico Bruns, Javier Read de Alaniz, Luciano F Boesel

Abstract readReview
In one paragraph

Review in Chemical Society reviews, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 34 papers.

0numbers the graph read from it
0cells of the map it votes in
34citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

34 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Article
  5. Article
  6. Article
  7. Article
  8. Article
  9. Stenhouse Zwitterion Photoswitches as Hydrogen-Bond Acceptors.Journal of the American Chemical Society · 2026
    Article
  10. Article
  11. Article
  12. Article
  13. Article
  14. Article
  15. Reversible Photoswitching of Donor-Acceptor Stenhouse Adducts in Water.Journal of the American Chemical Society · 2026
    Article
  16. Article
  17. Designing Physical Unclonable Functions From Optically Active Materials.Advanced materials (Deerfield Beach, Fla.) · 2025
    Review
  18. Article
  19. Article
  20. Future Frontiers in Bioinspired Implanted Biomaterials.Advanced materials (Deerfield Beach, Fla.) · 2025
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Michèle ClercEmpa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Biomimetic Membranes and Textiles, 9014 St. Gallen, Switzerland. luciano.boesel@empa.ch.ORCID http://orcid.org/0000-0003-3252-5410
Sara SandlassDepartment of Chemical Engineering, University of California, Santa Barbara, California 93106, USA.ORCID http://orcid.org/0000-0001-7649-0438
Omar Rifaie-GrahamDepartment of Chemistry, School of Physical and Chemical Sciences, Queen Mary University of London, London E1 4NS, UK.ORCID http://orcid.org/0000-0003-1403-0537
Julie A PetersonDepartment of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, USA. javier@chem.ucsb.edu.ORCID http://orcid.org/0000-0001-5758-4017
Nico BrunsDepartment of Pure and Applied Chemistry, University of Strathclyde, Glasgow G1 1XL, UK.ORCID http://orcid.org/0000-0001-6199-9995
Javier Read de AlanizDepartment of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, USA. javier@chem.ucsb.edu.ORCID http://orcid.org/0000-0003-2770-9477
Luciano F BoeselEmpa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Biomimetic Membranes and Textiles, 9014 St. Gallen, Switzerland. luciano.boesel@empa.ch.ORCID http://orcid.org/0000-0003-4481-9651

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Donor-acceptor Stenhouse adduct (DASA) photoswitches have gained a lot of attention since their discovery in 2014. Their negative photochromism, visible light absorbance, synthetic tunability, and the large property changes between their photoisomers make them attractive candidates over other commonly used photoswitches for use in materials with responsive or adaptive properties. The development of such materials and their translation into advanced technologies continues to widely impact forefront materials research, and DASAs have thus attracted considerable interest in the field of visible-light responsive molecular switches and dynamic materials. Despite this interest, there have been challenges in understanding their complex behavior in the context of both small molecule studies and materials. Moreover, incorporation of DASAs into polymers can be challenging due to their incompatibility with the conditions for most common polymerization techniques. In this review, therefore, we examine and critically discuss the recent developments and challenges in the field of DASA-containing polymers, aiming at providing a better understanding of the interplay between the properties of both constituents (matrix and photoswitch). The first part summarizes current understanding of DASA design and switching properties. The second section discusses strategies of incorporation of DASAs into polymers, properties of DASA-containing materials, and methods for studying switching of DASAs in materials. We also discuss emerging applications for DASA photoswitches in polymeric materials, ranging from light-responsive drug delivery systems, to photothermal actuators, sensors and photoswitchable surfaces. Last, we summarize the current challenges in the field and venture on the steps required to explore novel systems and expand both the functional properties and the application opportunities of DASA-containing polymers.

Identifiers

PMID37905554
PMCPMC10680135

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.