Altering the Localization of an Unpaired Spin in a Formal Ni(V) Species.

Ayushi Awasthi, Sharath Chandra Mallojjala, Rakesh Kumar, Raju Eerlapally, Jennifer S Hirschi, Apparao Draksharapu

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Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

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1citing papers in PubMed

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1 citing paper in PubMed.

Spectroscopically Deciphering the Formation and Reactivity of a High-Valent Ni(IV)ClJACS Au · 2026
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Authors and funding

6 authors.

Ayushi AwasthiSouthern Laboratories-208 A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208016, India.ORCID https://orcid.org/0000-0002-5135-8366

Sharath Chandra MallojjalaDepartment of Chemistry, Binghamton University, Binghamton, New York, 13902, USA.ORCID https://orcid.org/0000-0003-0446-792X

Rakesh KumarSouthern Laboratories-208 A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208016, India.ORCID https://orcid.org/0000-0003-1658-1738

Raju EerlapallySouthern Laboratories-208 A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208016, India.ORCID https://orcid.org/0000-0003-3720-9097

Jennifer S HirschiDepartment of Chemistry, Binghamton University, Binghamton, New York, 13902, USA.ORCID https://orcid.org/0000-0002-3470-0561

Apparao DraksharapuSouthern Laboratories-208 A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208016, India.ORCID https://orcid.org/0000-0001-7897-3230

Funding

Mechanistic Investigation into Modern Catalytic ReactionsR35GM147183 · NIGMS · STATE UNIVERSITY OF NY,BINGHAMTON · PI Jennifer Hirschi · 2022 to 2026

$1.7M

NIGMS NIH HHS R35 GM147183NIH HHS R35GM147183

6 · The paper itself

Abstract

The participation of both ligand and the metal center in the redox events has been recognized as one of the ways to attain the formal high valent complexes for the late 3d metals, such as Ni and Cu. Such an approach has been employed successfully to stabilize a Ni(III) bisphenoxyl diradical species in which there exist an equilibrium between the ligand and the Ni localized resultant spin. The present work, however, broadens the scope of the previously reported three oxidized equivalent species by conveying the approaches that tend to affect the reported equilibrium in CH

Indexed as

exogenous ligandshigh-valent nickelreactive intermediatesredox-active ligandsalen

Identifiers

PMID37903027

DOI10.1002/chem.202302824

PMCPMC10841873

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