ReviewAdvanced materials (Deerfield Beach, Fla.)2024
Thiomolybdate Clusters: From Homogeneous Catalysis to Heterogenization and Active Sites.
Review in Advanced materials (Deerfield Beach, Fla.), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Impact of Organo-Functionalization on the Light-Driven Hydrogen Evolution Reactivity of Molecular Molybdenum Sulfides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- 4CzIPN Photosensitizes the Cobaloxime-Catalyzed Light-Driven Hydrogen Evolution Reaction.ChemSusChem · 2026Article
- Article
- Electrostatic Confinement of Photosensitizers within Molybdenum-Sulfur Cluster-Based Supramolecular Matrices for Efficient Dual-Photocatalysis: Hydrogen Evolution and Trifluoromethylation.Journal of the American Chemical Society · 2026Article
- Atomically Precise Cluster Cocatalysts: Missing Link toward Heterogenized Photocatalytic Systems.ACS nano · 2026Review
- Proton Reduction with a Cobalt-Doped Thiomolybdate Cluster: A Structural and Functional Model of Co-Doped MoSJournal of the American Chemical Society · 2025Article
- Catalytic reduction of aldehydic and nitro groups of nitro-benzaldehyde derivatives by silver nanoparticle-containing smart alginate-poly(RSC advances · 2025Article
- Direct Anchoring of Molybdenum Sulfide Molecular Catalysts on Antimony Selenide Photocathodes for Solar Hydrogen Production.ACS energy letters · 2024Article
- Synthesis of polyoxothiometalates through site-selective post-editing sulfurization of polyoxometalates.Chemical science · 2024Article
- A thiomolybdate cluster for visible-light-driven hydrogen evolution: comparison of homogeneous and heterogeneous approaches.Sustainable energy & fuels · 2024Article
- Thiomolybdate Clusters: From Homogeneous Catalysis to Heterogenization and Active Sites.Advanced materials (Deerfield Beach, Fla.) · 2024Review
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
Thiomolybdates are molecular molybdenum-sulfide clusters formed from Mo centers and sulfur-based ligands. For decades, they have attracted the interest of synthetic chemists due to their unique structures and their relevance in biological systems, e.g., as reactive sites in enzymes. More recently, thiomolybdates are explored from the catalytic point of view and applied as homogeneous and molecular mimics of heterogeneous molybdenum sulfide catalysts. This review summarizes prominent examples of thiomolybdate-based electro- and photocatalysis and provides a comprehensive analysis of their reactivities under homogeneous and heterogenized conditions. Active sites of thiomolybdates relevant for the hydrogen evolution reaction are examined, aiming to shed light on the link between cluster structure and performance. The shift from solution-phase to surface-supported thiomolybdates is discussed with a focus on applications in electrocatalysis and photocatalysis. The outlook highlights current trends and emerging areas of thiomolybdate research, ending with a summary of challenges and key takeaway messages based on the state-of-the-art research.
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Registered trials
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