Evidence map›Paper›PMID 37875394›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2023

Deciphering Electrolyte Dominated Na

Guiyu Liu, Zhiqiang Wang, Huimin Yuan, Chunliu Yan, Rui Hao, Fangchang Zhang, Wen Luo, Hongzhi Wang, Yulin Cao, Shuai Gu and 6 more

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
15.0field-weighted citation impact, top 1% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed, 115 citations in OpenAlex.

  1. Article
  2. Engineering Solvent-Anion Interactions via Asymmetric Ethers for 200 Wh KgAngewandte Chemie (International ed. in English) · 2026
    Article
  3. Solvation-Pore Coupling Governs Fast Na Storage in Hard Carbon Anodes.Small (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  4. Article
  5. Article
  6. Article
  7. Article
  8. Article
  9. Article
  10. Deciphering Electrolyte Dominated NaAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

16 authors at 1 institution in 1 country.

Guiyu LiuDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Zhiqiang WangDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Huimin YuanDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Chunliu YanDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Rui HaoDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Fangchang ZhangDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Wen LuoDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Hongzhi WangDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Yulin CaoDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Shuai GuDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Chun ZengDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Yingzhi LiDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Zhenyu WangDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Ning QinDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Guangfu LuoDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.
Zhouguang LuDepartment of Materials Science and Engineering, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, Southern University of Science and Technology, Shenzhen, 518055, China.ORCID https://orcid.org/0000-0003-3769-9356
Southern University of Science and Technology · CN

Funding

Basic Research Project of the Science and Technology Innovation Commission of Shenzhen JCYJ20220818100418040Guangdong Provincial Key Laboratory of Computational Science and Material Design 2019B030301001Introduced Innovative R&D Team of Guangdong 2017ZT07C062National Natural Science Foundation of China U22A20439Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials ZDSYS20200421111401738Shenzhen Science and Technology Innovation Committee JCYJ20200109141412308
6 · The paper itself

Abstract

Although hard carbon (HC) demonstrates superior initial Coulombic efficiency, cycling durability, and rate capability in ether-based electrolytes compared to ester-based electrolytes for sodium-ion batteries (SIBs), the underlying mechanisms responsible for these disparities remain largely unexplored. Herein, ex situ electron paramagnetic resonance (EPR) spectra and in situ Raman spectroscopy are combined to investigate the Na storage mechanism of HC under different electrolytes. Through deconvolving the EPR signals of Na in HC, quasi-metallic-Na is successfully differentiated from adsorbed-Na. By monitoring the evolution of different Na species during the charging/discharging process, it is found that the initial adsorbed-Na in HC with ether-based electrolytes can be effectively transformed into intercalated-Na in the plateau region. However, this transformation is obstructed in ester-based electrolytes, leading to the predominant storage of Na in HC as adsorbed-Na and pore-filled-Na. Furthermore, the intercalated-Na in HC within the ether-based electrolytes contributes to the formation of a uniform, dense, and stable solid-electrolyte interphase (SEI) film and eventually enhances the electrochemical performance of HC. This work successfully deciphers the electrolyte-dominated Na

Indexed as

electrolyteelectron paramagnetic resonancehard carbonin situ Ramansodium storage mechanism

Identifiers

PMID37875394
PMCPMC10754077
OpenAlexW4387898422

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.