ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2023
Synergistically Boosting the Circularly Polarized Luminescence of Functionalized Pillar[5]arenes by Polymerization and Aggregation.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed, 42 citations in OpenAlex.
- Aggregated-state arylborane-pillar[5]arenes: a new three-in-one method for the modulation of circularly polarized luminescence.Chemical science · 2026Article
- Temperature-Responsive Supramolecular Chiral Switch Achieved by Macrocyclic Confinement.JACS Au · 2026Article
- Synthesis and host-guest chemistry of a thiophene-extended pillar[6]arene: toward applications in nitroaromatics removal and cell imaging.Frontiers in chemistry · 2026Article
- Quantum Chemistry Calculations of Circularly Polarized Luminescence (CPL): From Spectral Modeling to Molecular Design.Chemical reviews · 2025Review
- Self-assembling macrocyclic pillar[5]arene into toroidal, Möbius-strip-like nanoring and circularly polarized luminescence.National science review · 2025Article
- Artificial light harvesting systems based on novel AIEgen-branched rotaxane dendrimers for photocatalyzed functionalization of C-H bonds.Chemical science · 2025Article
- Configurationally Stepping Confinement Achieved Tunable Chiral Near-Infrared Luminescence Supramolecular Phenothiazine Organic Framework.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Enantiopure trigonal bipyramidal coordination cages templated by in situ self-organized DNature communications · 2024Article
- Recent Developments of Fluorescence Sensors Constructed from Pillar[Sensors (Basel, Switzerland) · 2024Review
- Synergistically Boosting the Circularly Polarized Luminescence of Functionalized Pillar[5]arenes by Polymerization and Aggregation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
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Authors and funding
5 authors at 2 institutions in 1 country.
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Abstract
Supramolecular polymers based on chiral macrocycles have attracted increasing attention in the field of circularly polarized luminescence (CPL) owing to their unique properties. However, the construction of macrocyclic supramolecular polymers with highly efficient CPL properties in aggregate states still remains challenging. Herein, w e constructed a class of macrocycle-based coordination polymers by combining the planar chiral properties of pillar[5]arene with the excellent fluorescence properties of aggregation-induced emission luminogens. The formation of polymers enhances both the fluorescence and chiral properties, resulting in chiral supramolecular polymers with remarkable CPL properties. Increasing the aggregation degree of the polymers can further improve their CPL properties, as evidenced by a 21-fold increase in the dissymmetry factor and an over 25-fold increase in the fluorescence quantum yield in the aggregate state compared to the solution state. Such a synergistic effect of polymerization- and aggregation-enhanced CPL can be explained by the restriction of intramolecular motions and aggregation-induced conformation confinement. This work provides a promising method for developing highly efficient CPL supramolecular polymers.
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