ArticleNature communications2023
Highly efficient color-tunable organic co-crystals unveiling polymorphism, isomerism, delayed fluorescence for optical waveguides and cell-imaging.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Geometric Evolution of Perylene-Based Intermolecular π-π Dimers Toward Static and Dynamic Multicolor Emission.Angewandte Chemie (International ed. in English) · 2026Article
- Breaking the Fixed Output: Harnessing Photonic Reabsorption and Photothermal Effects for Tunable NIR Waveguiding in a Flexible Organic Crystal.Angewandte Chemie (International ed. in English) · 2026Article
- Inclusion co-crystals based on Tröger's base molecular box for thermally activated delayed fluorescence.Nature communications · 2026Article
- Stimuli-Responsive Triplet Emission and X-Ray Scintillation via Reversible Structural Switching in Pyromellitic Diimide Cocrystals.Angewandte Chemie (International ed. in English) · 2026Article
- Resonator-based add-drop filters enabled by flexible polymorphic crystals with TADF-RTP motifs.Chemical science · 2026Article
- Near-Infrared Cocrystal Nanofluorophore with Enhanced Two-Photon Absorption Cross Sections.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Beyond Cocrystals: Hierarchical Functional Assemblies via Noncovalent Synthesis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Tunable Photoluminescent and Photothermal Properties of Organic Cocrystals Containing Hydrogen-Bonded Interlocked Planar Molecules.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Tuning of Optoelectronic Properties in Oligo(phenyleneethynylene)-Based Cocrystals through Modulation of Charge-Transfer Interactions.ACS omega · 2025Article
- Article
- Single-component-based multicolor emissions enabled by symmetry breaking.Nature communications · 2025Article
- Optical Waveguiding Charge-Transfer Cocrystals: Examining the Impact of Molecular Rotations on Their Photoluminescence.Journal of the American Chemical Society · 2025Article
- Article
- The Delayed Box: Biphenyl Bisimide Cyclophane, a Supramolecular Nano-environment for the Efficient Generation of Delayed Fluorescence.Journal of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
Photofunctional co-crystal engineering strategies based on donor-acceptor π-conjugated system facilitates expedient molecular packing, consistent morphology, and switchable optical properties, conferring synergic 'structure-property relationship' for optoelectronic and biological functions. In this work, a series of organic co-crystals were formulated using a twisted aromatic hydrocarbon (TAH) donor and three diverse planar acceptors, resulting in color-tunable solid and aggregated state emission via variable packing and through-space charge-transfer interactions. While, adjusting the strength of acceptors, a structural transformation into hybrid stacking modes ultimately results in color-specific polymorphs, a configurational cis-isomer with very high photoluminescence quantum yield. The cis-isomeric co-crystal exhibits triplet-harvesting thermally activated delayed fluorescence (TADF) characteristics, presenting a key discovery in hydrocarbon-based multicomponent systems. Further, 1D-microrod-shaped co-crystal acts as an efficient photon-transducing optical waveguides, and their excellent dispersibility in water endows efficient cellular internalization with bright cell imaging performances. These salient approaches may open more avenues for the design and applications of TAH based co-crystals.
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Registered trials
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