ArticleNature communications2023
Highly active, ultra-low loading single-atom iron catalysts for catalytic transfer hydrogenation.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
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- A Self-Cascade Nanozyme of Metformin-Stabilized Amorphous Iron Oxide With Ultrahigh Fe(II) for Potent Tumor Therapy at Ultralow Dose.Angewandte Chemie (International ed. in English) · 2026Article
- Stabilizing sub-nanoporous zinc metal-organic frameworks in SnTe thermoelectrics for high-temperature power generation.Chemical science · 2026Article
- Dynamic chloride coordination enables selective pulsed electrocatalytic upcycling of 4-chlorophenol on FeNNature communications · 2026Article
- Tuning the metal-support interactions in transition metal-anchored heteroatom-doped graphene single-atom catalysts.Physical chemistry chemical physics : PCCP · 2026Review
- Fe-(μ-O)-Zn dual-atom boosting C-C coupling for direct oxidation of methane to acetic acid using ONature communications · 2025Article
- A Biomimetic Twisting Strategy Enables Efficient Electrocatalytic Oxidation of Energy-Dense Hydrazine Hydrate on FeNJournal of the American Chemical Society · 2025Article
- Carbon Decorated Pd Species within Zeolite for Selective Furfural Hydrogenation.ACS central science · 2025Article
- Photocatalytic Semiconductor-Metal Hybrid Nanoparticles: Single-Atom Catalyst Regime Surpasses Metal Tips.ACS nano · 2025Article
- Entropy engineering activation of UiO-66 for boosting catalytic transfer hydrogenation.Nature communications · 2025Article
- Topological transformation of microbial proteins into iron single-atom sites for selective hydrogen peroxide electrosynthesis.Nature communications · 2024Article
- Assembly and Valence Modulation of Ordered Bimetallic MOFs for Highly Efficient Electrocatalytic Water Oxidation.Molecules (Basel, Switzerland) · 2024Article
- Photocatalytic Hydrogenation of Alkenes Using Water as Both the Reductant and the Proton Source.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Single-Atom Co-NJACS Au · 2024Article
- Combination of nanoparticles with single-metal sites synergistically boosts co-catalyzed formic acid dehydrogenation.Nature communications · 2024Article
- Enable biomass-derived alcohols mediated alkylation and transfer hydrogenation.Nature communications · 2024Article
- Defects tune the acidic strength of amorphous aluminosilicates.Nature communications · 2024Article
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Authors and funding
15 authors.
Funding
Abstract
Highly effective and selective noble metal-free catalysts attract significant attention. Here, a single-atom iron catalyst is fabricated by saturated adsorption of trace iron onto zeolitic imidazolate framework-8 (ZIF-8) followed by pyrolysis. Its performance toward catalytic transfer hydrogenation of furfural is comparable to state-of-the-art catalysts and up to four orders higher than other Fe catalysts. Isotopic labeling experiments demonstrate an intermolecular hydride transfer mechanism. First principles simulations, spectroscopic calculations and experiments, and kinetic correlations reveal that the synthesis creates pyrrolic Fe(II)-plN
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