ReviewChemical science2023
Carbon-carbon bond activation by Mg, Al, and Zn complexes.
Review in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
5 citing papers in PubMed.
- Photo-induced terminal alkyne insertion into arene ring to synthesize boron-doped polycycles.Chemical science · 2026Article
- Gallylene-Mediated C-C Bond Activation of Diphenylcyclopropenone and Chalcogen Atom Insertion into a Ga-C Bond.ACS organic & inorganic Au · 2026Article
- Crystalline Silaspiropentane and Its Rearrangement to Silacyclobutane.Organic letters · 2026Article
- Mechanochemical Synthesis of a Sodium Anion Complex [NaInorganic chemistry · 2024Article
- Lewis acid catalyzed [4+2] annulation of bicyclobutanes with dienol ethers for the synthesis of bicyclo[4.1.1]octanes.Chemical science · 2024Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Examples of carbon-carbon bond activation reactions at Mg, Al, and Zn are described in this review. Several distinct mechanisms for C-C bond activation at these metals have been proposed, with the key C-C bond activation step occurring by (i) α-alkyl elimination, (ii) β-alkyl elimination, (iii) oxidative addition, or (iv) an electrocyclic reaction. Many of the known pathways involve an overall 2-electron redox process. Despite this, the direct oxidative addition of C-C bonds to these metals is relatively rare, instead most reactions occur through initial installation of the metal on a hydrocarbon scaffold (
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.