Evidence map›Paper›PMID 37860650›Full record

ArticleChemical science2023

On the σ-complex character of bis(gallyl)/digallane transition metal species.

Till L Kalkuhl, Lei Qin, Lili Zhao, Gernot Frenking, Terrance J Hadlington

Abstract read
In one paragraph

Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Snapshots of Cooperative Trimetallic Alkene Hydrogenation.Journal of the American Chemical Society · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Till L KalkuhlFakultät für Chemie, Technische Universität München Lichtenberg Strasse 4 85747 Garching Germany terrance.hadlington@tum.de.
Lei QinInstitute of Advanced Synthesis, School of Chemistry and Molecular Engineering State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University Nanjing China ias_llzhao@njtech.edu.cn.
Lili ZhaoInstitute of Advanced Synthesis, School of Chemistry and Molecular Engineering State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University Nanjing China ias_llzhao@njtech.edu.cn.ORCID https://orcid.org/0000-0003-2580-6919
Gernot FrenkingInstitute of Advanced Synthesis, School of Chemistry and Molecular Engineering State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University Nanjing China ias_llzhao@njtech.edu.cn.ORCID https://orcid.org/0000-0003-1689-1197
Terrance J HadlingtonFakultät für Chemie, Technische Universität München Lichtenberg Strasse 4 85747 Garching Germany terrance.hadlington@tum.de.ORCID https://orcid.org/0000-0002-4131-8870

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

σ-complexes of homoatomic E-E bonds are key intermediates in catalytically relevant oxidative addition reactions, but are as yet unknown for the group 13 elements. Here, stable species best described as σ-complexes of a 1,2-dichlorodigallane derivative with Ni and Pd are reported. They are readily accessed through the combination of a 1,2-dichlorodigallane derivative, which features chelating phosphine functionalities, with Ni

Identifiers

PMID37860650
PMCPMC10583741

What OpenQuestion holds

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.