Evidence map›Paper›PMID 37856668›Full record

ArticleAngewandte Chemie (International ed. in English)2023

Rhodium-Catalyzed Asymmetric Synthesis of 1,2-Disubstituted Allylic Fluorides.

Fuad O Usman, Achyut R Gogoi, Jason C Mixdorf, Osvaldo Gutierrez, Hien M Nguyen

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. JACS Au · 2026
    Article
  2. Article
  3. Article
  4. Cooperative Catalysis in StereoselectiveJournal of the American Chemical Society · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Fuad O UsmanDepartment of Chemistry, Wayne State University, Detroit, MI 48202, USA.
Achyut R GogoiDepartment of Chemistry, Texas A&M University, College Station, TX 77843, USA.
Jason C MixdorfDepartment of Medical Physics, University of Wisconsin School of Medicine and Public Health, Madison, WI 53705, USA.
Osvaldo GutierrezDepartment of Chemistry, Texas A&M University, College Station, TX 77843, USA.
Hien M NguyenDepartment of Chemistry, Wayne State University, Detroit, MI 48202, USA.ORCID https://orcid.org/0000-0002-7626-8439

Funding

Tailoring Structures of Sulfated Oligosaccharides for Modulating Heparanase ActivityR01GM098285 · NIGMS · WAYNE STATE UNIVERSITY · PI NGUYEN, HIEN M · 2012 to 2022
$3.5M
New Directions in Sustainable Open-Shell Radical C-C Bond Formations Enabled by Merging Modern Computational and Experimental MethodsR35GM137797 · NIGMS · UNIV OF MARYLAND, COLLEGE PARK · PI Osvaldo Gutierrez · 2020 to 2026
$2.7M
Development of Catalytic Glycosylations and Biologically Important GlycosaminoglycansR35GM149213 · NIGMS · WAYNE STATE UNIVERSITY · PI Hien M Nguyen · 2023 to 2026
$1.9M
500 MHz NMR SpectrometerS10OD028488 · OD · WAYNE STATE UNIVERSITY · PI ALLEN, MATTHEW J · 2021 to 2021
$600k
NIGMS NIH HHS R01 GM098285NIGMS NIH HHS R35 GM137797NIGMS NIH HHS R35GM137797NIGMS NIH HHS R35 GM149213NIGMS NIH HHS R35GM149213NIH HHS S10 OD028488
6 · The paper itself

Abstract

Although there are many methods for the asymmetric synthesis of monosubstituted allylic fluorides, construction of enantioenriched 1,2-disubstituted allylic fluorides has not been reported. To address this gap, we report an enantioselective synthesis of 1,2-disubstituted allylic fluorides using chiral diene-ligated rhodium catalyst, Et

Indexed as

1,2-Disubstituted Allylic FluoridesAsymmetric FluorinationDFTRhodium Catalysis

Identifiers

PMID37856668
PMCPMC11069351

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.