ArticleACS nano2023
Electrochromism in Isoreticular Metal-Organic Framework Thin Films with Record High Coloration Efficiency.
Article in ACS nano, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Influence of arylene diimide linker aromaticity on the electrochemical performance of redox-active metal-organic framework cathodes for lithium-ion storage.Journal of materials chemistry. A · 2026Article
- Crystalline Framework Electrodes for Hybrid Supercapacitors: Device-Oriented Design From Metal-Organic and Covalent Organic Frameworks to Practical Hybrids.Chemical record (New York, N.Y.) · 2026Review
- Ion Diffusion and (Photo)redox Conductivity in a Covalent Organic Framework.Journal of the American Chemical Society · 2026Article
- Multidirectional color palette of electrochromic metal-organic frameworks.National science review · 2025Article
- Rapid Redox Hopping Charge Transfer and Electrochromism in a Multivariate Metal-Organic Framework.Journal of the American Chemical Society · 2025Article
- Switching between Limiting Charge Extraction Regimes in an Illuminated Semiconductor-Metal-Organic Framework Junction.Journal of the American Chemical Society · 2025Article
- Advancements in Electrochromic Technology for Multifunctional Flexible Devices.Materials (Basel, Switzerland) · 2025Review
- Efficiently regulating the electrochromic behavior of naphthalene-diimide-based zirconium-organic frameworks through linker installation.Nature communications · 2025Article
- High-Efficiency and High-Capacity Aqueous Electrochromic Energy Storage Devices Enabled by Decoupled Titanium Oxide/Viologen Derivative Hybrid Materials.Research (Washington, D.C.) · 2025Article
- Alkali-Stable Metal-Organic Frameworks with Enhanced Electroconductivity for Black-Brown Electrochromic Energy Storage Smart Window.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- The Molecular Nature of Redox-Conductive Metal-Organic Frameworks.Accounts of chemical research · 2024Article
- Diffusional Electron Transport Coupled to Thermodynamically Driven Electron Transfers in Redox-Conductive Multivariate Metal-Organic Frameworks.Journal of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The power of isoreticular chemistry has been widely exploited to engineer metal-organic frameworks (MOFs) with fascinating molecular sieving and storage properties but is underexplored for designing MOFs with tunable optoelectronic properties. Herein, three dipyrazole-terminated XDIs (X = PM (pyromellitic), N (naphthalene), or P (perylene); DI = diimide) with different lengths and electronic properties are prepared and employed as linkers for the construction of an isoreticular series of Zn-XDI MOFs with distinct electrochromism. The MOFs are grown on fluorine-doped tin oxide (FTO) as high-quality crystalline thin films and characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Due to the constituting electronically isolated XDI linkers, each member of the isoreticular thin film series exhibits two reversible one-electron redox events, each at a distinct electrochemical potential. The orientation of the MOFs as thin films as well as their isoreticular nature results in identical cation-coupled electron hopping transport rates in all three materials, as demonstrated by comparable apparent electron diffusion coefficients,
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