Evidence map›Paper›PMID 37849695›Full record

ArticleRSC advances2023

Catalytic synthesis of renewable phenol derivatives from biobased furanic derivatives.

Adrien Ratier, Richail D Moulandou-Koumba, Mélanie Anizan, Sarah Behloul, Fréderic Guegan, Gilles Frapper, Quentin Blancart Remaury, Karine De Oliveira Vigier, Jianxia Zheng, François Jérôme

Abstract read
In one paragraph

Article in RSC advances, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Adrien RatierInstitut de Chimie des Milieux et Matériaux de Poitiers, Université de Poitiers, CNRS 1 rue Michel Brunet 86073 Poitiers France francois.jerome@univ-poitiers.fr frederic.guegan@univ-poitiers.fr.
Richail D Moulandou-KoumbaInstitut de Chimie des Milieux et Matériaux de Poitiers, Université de Poitiers, CNRS 1 rue Michel Brunet 86073 Poitiers France francois.jerome@univ-poitiers.fr frederic.guegan@univ-poitiers.fr.ORCID https://orcid.org/0000-0001-8278-9858
Mélanie AnizanInstitut de Chimie des Milieux et Matériaux de Poitiers, Université de Poitiers, CNRS 1 rue Michel Brunet 86073 Poitiers France francois.jerome@univ-poitiers.fr frederic.guegan@univ-poitiers.fr.
Sarah BehloulInstitut de Chimie des Milieux et Matériaux de Poitiers, Université de Poitiers, CNRS 1 rue Michel Brunet 86073 Poitiers France francois.jerome@univ-poitiers.fr frederic.guegan@univ-poitiers.fr.
Fréderic GueganInstitut de Chimie des Milieux et Matériaux de Poitiers, Université de Poitiers, CNRS 1 rue Michel Brunet 86073 Poitiers France francois.jerome@univ-poitiers.fr frederic.guegan@univ-poitiers.fr.
Gilles FrapperInstitut de Chimie des Milieux et Matériaux de Poitiers, Université de Poitiers, CNRS 1 rue Michel Brunet 86073 Poitiers France francois.jerome@univ-poitiers.fr frederic.guegan@univ-poitiers.fr.ORCID https://orcid.org/0000-0001-5177-6691
Quentin Blancart RemauryInstitut de Chimie des Milieux et Matériaux de Poitiers, Université de Poitiers, CNRS 1 rue Michel Brunet 86073 Poitiers France francois.jerome@univ-poitiers.fr frederic.guegan@univ-poitiers.fr.
Karine De Oliveira VigierInstitut de Chimie des Milieux et Matériaux de Poitiers, Université de Poitiers, CNRS 1 rue Michel Brunet 86073 Poitiers France francois.jerome@univ-poitiers.fr frederic.guegan@univ-poitiers.fr.ORCID https://orcid.org/0000-0003-3613-7992
Jianxia ZhengEco-Efficient Products and Process Laboratory SOLVAY/CNRS 3966 Jin Du Rd., Xin Zhuang Industrial Zone Shanghai 201108 China.
François JérômeInstitut de Chimie des Milieux et Matériaux de Poitiers, Université de Poitiers, CNRS 1 rue Michel Brunet 86073 Poitiers France francois.jerome@univ-poitiers.fr frederic.guegan@univ-poitiers.fr.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Here, we study a sequence Diels-Alder/aromatization reaction between biobased furanic derivatives and alkynes, paving the way to renewable phenols. Guided by DFT calculations, we revealed that, in the case of dimethylfuran, the methyl group can migrate during the aromatization step, making this substrate also eligible to access renewable phenols. This reaction has been then successfully transposed to furfural and furfuryl alcohol, allowing molecular diversity and complexity to be created on phenol ring starting from two cheap biobased furanic derivatives available on large scale.

Identifiers

PMID37849695
PMCPMC10578459

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.