ArticleNature communications2023
Atomic high-spin cobalt(II) center for highly selective electrochemical CO reduction to CH
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 32 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
32 citing papers in PubMed, 145 citations in OpenAlex.
- Unveiling Structure-Activity Relationship With Structurally Defined and Stabilized Cu-Based Molecular Hybrid Electrocatalysts in COExploration (Beijing, China) · 2026Article
- Side-Chain-Induced Interlayer Slipping in Metalloporphyrin COFs Enables Microenvironment and Spin-State Regulation for Photocatalytic COAdvanced materials (Deerfield Beach, Fla.) · 2026Article
- Synergistic Spin-Polarization Effect and Magnetic Exchange Interaction of Core/Shell Structure for Bifunctional Oxygen Electrocatalysis.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Spin-Dominated Electroreduction of Oxygen to Hydrogen Peroxide: A Case Study With Molecular Model Catalysts.Angewandte Chemie (International ed. in English) · 2026Article
- Eco-Friendly Synthesis of Cobalt Phthalocyanine for High-EfficiencyChemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Electronic Transport in Porous Nanocrystals Enables Ultrasensitive Consistent Detection of Sulfur Dioxide under Variable Humidity.Journal of the American Chemical Society · 2026Article
- Electrolyte-Replacement-Free Continuous Electrocatalytic Desalination Coupled With COAngewandte Chemie (International ed. in English) · 2026Article
- Spin-state engineering of single-atom cobalt catalysts via carbon nanotube supports enhances catalytic activity.Nature communications · 2026Article
- Spin-State Modulation of Atomic Iron Sites Enables Efficient COAngewandte Chemie (International ed. in English) · 2026Article
- Operando Cu Aggregation-Induced Spin State Modulation in Fe-Cu Single Atom Catalyst for Enhanced Tandem Electrochemical Nitrate Reduction Reaction.Journal of the American Chemical Society · 2026Article
- Bidirectional catalysts with dual-atom dynamic d-band centre modulation and support self-reconstruction for de/hydrogenation in MgHNature communications · 2026Article
- Support-Induced Interfacial Effects Steer Methanol Selectivity in COAngewandte Chemie (International ed. in English) · 2026Article
- Efficient CONature nanotechnology · 2026Article
- Decoupling of Spin and Non-Spin Effects From Electronic Structure Modulation for Oxygen Electrocatalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Review
- Integrative catalytic pairs driving complex chemical reactions.Nature reviews. Chemistry · 2025Review
- Manipulating spin-state conversion to promote asymmetric d-p orbital hybridization for high-efficiency nitrate electroreduction to ammonia.Chemical science · 2025Article
- Spin Engineering of Dual-Atom Site Catalysts for Efficient Electrochemical Energy Conversion.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Deformed One-Dimensional Covalent Organic Polymers for Enhanced CO Electroreduction to Methanol.ACS nano · 2025Article
- Tuning Transition Metal 3d Spin state on Single-atom Catalysts for Selective Electrochemical COAdvanced materials (Deerfield Beach, Fla.) · 2025Article
- Regulating the electrocatalytic active centers for accelerated proton transfer towards efficient CONational science review · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
17 authors at 7 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In this work, via engineering the conformation of cobalt active center in cobalt phthalocyanine molecular catalyst, the catalytic efficiency of electrochemical carbon monoxide reduction to methanol can be dramatically tuned. Based on a collection of experimental investigations and density functional theory calculations, it reveals that the electron rearrangement of the Co 3d orbitals of cobalt phthalocyanine from the low-spin state (S = 1/2) to the high-spin state (S = 3/2), induced by molecular conformation change, is responsible for the greatly enhanced CO reduction reaction performance. Operando attenuated total reflectance surface-enhanced infrared absorption spectroscopy measurements disclose accelerated hydrogenation of CORR intermediates, and kinetic isotope effect validates expedited proton-feeding rate over cobalt phthalocyanine with high-spin state. Further natural population analysis and density functional theory calculations demonstrate that the high spin Co
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.