Evidence map›Paper›PMID 37845252›Full record

ArticleNature communications2023

Rationalizing kinetic behaviors of isolated boron sites catalyzed oxidative dehydrogenation of propane.

Hao Tian, Wenying Li, Linhai He, Yunzhu Zhong, Shutao Xu, Hai Xiao, Bingjun Xu

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
1.3field-weighted citation impact, top 21% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 21 citations in OpenAlex.

  1. Article
  2. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 3 institutions in 1 country.

Hao TianCollege of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China.ORCID http://orcid.org/0000-0002-6666-290X
Wenying LiDepartment of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Tsinghua University, Beijing, 100084, China.
Linhai HeNational Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
Yunzhu ZhongCollege of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China.
Shutao XuNational Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.ORCID http://orcid.org/0000-0003-4722-8371
Hai XiaoDepartment of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Tsinghua University, Beijing, 100084, China.ORCID http://orcid.org/0000-0001-9399-1584
Bingjun XuCollege of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China. b_xu@pku.edu.cn.ORCID http://orcid.org/0000-0002-2303-257X
Peking University · CNDalian Institute of Chemical Physics · CNTsinghua University · CN

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22108006National Natural Science Foundation of China (National Science Foundation of China) 22172001
6 · The paper itself

Abstract

Boron-based catalysts exhibit high alkene selectivity in oxidative dehydrogenation of propane (ODHP) but the mechanistic understanding remains incomplete. In this work, we show that the hydroxylation of framework boron species via steaming not only enhances the ODHP rate on both B-MFI and B-BEA, but also impacts the kinetics of the reaction. The altered activity, propane reaction order and the activation energy could be attributed to the hydrolysis of framework [B(OSi≡)

Identifiers

PMID37845252
PMCPMC10579386
OpenAlexW4387666821

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.