Evidence map›Paper›PMID 37842679›Full record

ArticleRSC advances2023

A modified Beckmann rearrangement for the facile synthesis of amidines and imidates

James A Vogel, Kirya F Miller, Eunjeong Shin, Jenna M Krussman, Patrick R Melvin

Abstract read
In one paragraph

Article in RSC advances, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

James A VogelDepartment of Chemistry, Bryn Mawr College Bryn Mawr Pennsylvania 19010 USA prmelvin@brynmawr.edu.
Kirya F MillerDepartment of Chemistry, Bryn Mawr College Bryn Mawr Pennsylvania 19010 USA prmelvin@brynmawr.edu.
Eunjeong ShinDepartment of Chemistry, Bryn Mawr College Bryn Mawr Pennsylvania 19010 USA prmelvin@brynmawr.edu.
Jenna M KrussmanDepartment of Chemistry, Bryn Mawr College Bryn Mawr Pennsylvania 19010 USA prmelvin@brynmawr.edu.
Patrick R MelvinDepartment of Chemistry, Bryn Mawr College Bryn Mawr Pennsylvania 19010 USA prmelvin@brynmawr.edu.ORCID https://orcid.org/0000-0003-2356-1989

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Herein, we report a modified Beckmann rearrangement using sulfone iminium fluoride (SIF) reagents to rapidly synthesize imidoyl fluoride intermediates. Subsequently, amidine and imidate products can be formed following the introduction of amine and alcohol nucleophiles, respectively. Overall, approximately 50 amidine and imidate products have been isolated in high yields utilizing mild conditions.

Identifiers

PMID37842679
PMCPMC10573916

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.