The Equilibrium Molecular Structure of Cyclic (Alkyl)(Amino) Carbene Copper(I) Chloride via Gas-Phase Electron Diffraction and Quantum Chemical Calculations.

Alexander V Belyakov, Ekaterina P Altova, Anatoliy N Rykov, Pavel Yu Sharanov, Igor F Shishkov, Alexander S Romanov

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Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it

0cells of the map it votes in

1citing papers in PubMed

0.6field-weighted citation impact, top 37% of its field

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 4 citations in OpenAlex.

Linear Gold(I) Halide Complexes with a Diamidocarbene Ligand: Synthesis, Reactivity, and Phosphorescence.Organometallics · 2024
Article

4 · The record

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PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 3 institutions in 2 countries.

Alexander V BelyakovSaint-Petersburg State Technological Institute, 190013 Saint Petersburg, Russia.ORCID 0000-0001-8575-8248

Ekaterina P AltovaDepartment of Chemistry, Moscow State University, 119992 Moscow, Russia.

Anatoliy N RykovDepartment of Chemistry, Moscow State University, 119992 Moscow, Russia.

Pavel Yu SharanovDepartment of Chemistry, Moscow State University, 119992 Moscow, Russia.

Igor F ShishkovDepartment of Chemistry, Moscow State University, 119992 Moscow, Russia.

Alexander S RomanovDepartment of Chemistry, University of Manchester, Oxford Rd., Manchester M13 9PL, UK.ORCID 0000-0003-2617-6402

Lomonosov Moscow State University · RUSt. Petersburg State Technological Institute · RUUniversity of Manchester · GB

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Copper-centered carbene-metal-halides (CMHs) with cyclic (alkyl)(amino) carbenes (CAACs) are bright phosphorescent emitters and key precursors in the synthesis of the highly promising class of the materials carbene-metal-amides (CMAs) operating via thermally activated delayed fluorescence (TADF). Aiming to reveal the molecular geometry for CMH phosphors in the absence of the intermolecular contacts, we report here the equilibrium molecular structure of the (CAAC)Cu(I)Cl (

Indexed as

carbene–metal–halidecomputationalcyclic (alkyl)(amino) carbeneelectron diffractionphosphorescence

Identifiers

PMID37836740

DOI10.3390/molecules28196897

PMCPMC10574683

OpenAlexW4387265029

What OpenQuestion holds

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.