ArticleChemical science2023
Acid-base responsive multifunctional poly(formyl sulfide)s through a facile catalyst-free click polymerization of aldehyde-activated internal diynes and dithiols.
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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Who cites it
3 citing papers in PubMed, 7 citations in OpenAlex.
- Photoresponsive DNA steganography for secure information transmission by nanopore.National science review · 2026Article
- Spontaneous amino-yne click polymerization enabled by pyridinium-activated alkynes toward p-π conjugated ionic polymers.Chemical science · 2025Article
- Recent Advances in Fluorescent Polyimides.Molecules (Basel, Switzerland) · 2024Review
Corrections and comments
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Authors and funding
7 authors at 3 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Acid-base equilibria play a critical role in biological processes and environmental systems. The development of innovative fluorescent polymeric materials to monitor acid-base equilibria is highly desirable. Herein, a novel catalyst-free click polymerization of aldehyde-activated internal diynes and dithiols was established, and exclusively Markovnikov poly(formyl sulfide)s (PFSs) with high molecular weights and moderate stereoregularity were produced in high yields. Because of the aromatic units and sulfur atoms in their main chains, these polymers possessed high refractive index values. By introducing the fluorene and aldehyde moieties, the resulting PFSs could act as a fluorescent sensor for sensitive hydrazine detection. Taking advantage of the reaction of the aldehyde group and hydrazine, imino-PFSs with remarkable and reversible fluorescence change through alternating fumigation with HCl and NH
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Registered trials
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