ArticleScience (New York, N.Y.)2023
Exploiting the Marcus inverted region for first-row transition metal-based photoredox catalysis.
Article in Science (New York, N.Y.), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 50 papers.
What it found
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Who cites it
50 citing papers in PubMed.
- Activating Triplet Excitons in COFs via Layer-Bridging Co Single Atoms for Photocatalytic HAngewandte Chemie (International ed. in English) · 2026Article
- Single-Atom Cu-Induced Electronic Localization Enhances Charge Transfer in g-CAdvanced materials (Deerfield Beach, Fla.) · 2026Article
- Influence of Transition-Metal Ions on the Photoisomerization of a Pentadentate Azopyridine Ligand: Interplay of Charge-Transfer and Metal-Centered States.Inorganic chemistry · 2026Article
- Number and Position of Methoxy Substituents Govern Photophysics and Visible-Light Photocatalysis in Earth-Abundant Cu(I) Complexes.ChemSusChem · 2026Article
- Selenoxanthylium Salts─Organic Photocatalysts for Low-Energy Photoredox Catalysis.Journal of the American Chemical Society · 2026Article
- Organic Photoredox-Catalyzed TEMPO Disproportionation: Development of a Mild Platform for In Situ Oxoammonium Ion Formation.The Journal of organic chemistry · 2026Article
- Metal-Centered Photoredox Catalysis using d6 Transition Metal-based Chromophores.Accounts of chemical research · 2026Article
- How Structural Subtleties Modulate Excited-State Lifetimes in Cyclometalated Cobalt(III) Complexes: Nonadiabatic Molecular Dynamics Study.Journal of computational chemistry · 2026Article
- Synthetic Mechanism of a Fe(II)Inorganic chemistry · 2026Article
- Supramolecular Modulation of Photoinduced Charge Transfer: Tuning Between Tunneling and Incoherent Hopping.Angewandte Chemie (International ed. in English) · 2026Article
- Kinetics vs Thermodynamics: Engineering Photoredox Reactivity from an Upper Excited State of FeJournal of the American Chemical Society · 2026Article
- Direct Quantum Yield Measurement of a Ligand-to-Metal Charge Transfer Photocatalyst via Cyclic Voltammetry.Journal of the American Chemical Society · 2026Article
- Hot-Carrier Injection and Millisecond Charge Separation from a Robust Heteroleptic Iron(II) Chromophore Immobilized on TiOJournal of the American Chemical Society · 2026Article
- Photochemical, electrochemical and electrophotochemical C-N bond-forming cross-coupling reactions.Nature reviews. Chemistry · 2026Review
- Base Metal Photocatalysts: A Bright Future in Photoredox Catalysis?Organometallics · 2026Article
- Viscosity-Controlled Magnetic Field Effects in Homogeneous Photoredox Catalysis Enabled by Ionic Liquids.Molecules (Basel, Switzerland) · 2026Article
- Photooxidative Copper(II) Catalysis for Promoting anti-Markovnikov Hydration of Alkenes.Nature communications · 2026Article
- Consistent and Generalizable Effective Model Hamiltonian Framework for Studying Nonadiabatic Dynamics in the Condensed Phase.Journal of chemical theory and computation · 2025Review
- Dramatic expansion of bimodal redox window of indigo by two-electron redox processes.Nature communications · 2025Article
- Electrochemical Oxidation of Aryl Boronic Acids via Fluoride Activation and Alternating Polarity Electrolysis for Aryl C-P Bond Formation.ChemElectroChem · 2025Article
Corrections and comments
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Authors and funding
9 authors.
Funding
Abstract
Second- and third-row transition metal complexes are widely employed in photocatalysis, whereas earth-abundant first-row transition metals have found only limited use because of the prohibitively fast decay of their excited states. We report an unforeseen reactivity mode for productive photocatalysis that uses cobalt polypyridyl complexes as photocatalysts by exploiting Marcus inverted region behavior that couples increases in excited-state energies with increased excited-state lifetimes. These cobalt (III) complexes can engage in bimolecular reactivity by virtue of their strong redox potentials and sufficiently long excited-state lifetimes, catalyzing oxidative C(sp
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Registered trials
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